900756

SLAP M

≥95%

• Synonim(y): 2-((Trimethylsilyl)methoxy)ethan-1-amine
• Wzór empiryczny (zapis Hilla): C₆H₁₇NOSi
• Numer CAS: 2093935-94-3
• Masa cząsteczkowa: 147.29
• Kod UNSPSC: 12352200

Właściwości

• Próba: ≥95%
• Postać: liquid
• temp. przechowywania: 2-8°C
• ciąg SMILES: NCCOC[Si](C)(C)C

Opis

Zastosowanie

When used with aliphatic or aromatic aldehydes, this silicon amine protocol (SLAP) reagent enables the photomediated synthesis of thiomorpholines and thiazepanes. For photocatalytic cross-coupling with this SLAP Reagent, Ir[(ppy)₂dtbbpy]PF6 (747769) is used with a recommended starting combination of Lewis acids Bi(OTf)₃ (633305) and Cu(OTf)₂ (283673) prior to subsequent substrate-specific optimization. This product was introduced in collaboration with the Bode Research Group and provides a tin-free alternative to SnAP (tin amine protocol) reagents and is well-suited for scale-up reactions.

Inne uwagi

• Lewis Acid Induced Toggle from Ir(II) to Ir(IV) Pathways in Photocatalytic Reactions: Synthesis of Thiomorpholines and Thiazepanes from Aldehydes and SLAP Reagents
• Silicon Amine Reagents for the Photocatalytic Synthesis of Piperazines from Aldehydes and Ketones

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Informacja o środkach bezpieczeństwa

• Kod klasy składowania: 10 - Combustible liquids
• Klasa zagrożenia wodnego (WGK): WGK 3
• Temperatura zapłonu (°F): Not applicable
• Temperatura zapłonu (°C): Not applicable