902225

Ir[dFMeppy]₂-(4,4′-dCF₃bpy)PF₆

≥95%

• Sinônimo(s): Photocatalyst
• Fórmula empírica (Notação de Hill): C₃₆H₂₂F₁₆IrN₄P
• Número CAS: 2229858-27-7
• Peso molecular: 1037.75
• Código UNSPSC: 41141700
• NACRES: NA.22

Propriedades

• Ensaio: ≥95%
• forma: powder
• adequação da reação: core: iridium; reaction type: Photocatalysis; reagent type: catalyst
• pf: >300 °C
• cadeia de caracteres SMILES: FC1=CC(F)=C2C3=CC=C(C=[N]3[Ir+3]45([C-]2=C1)([C-]6=CC(F)=CC(F)=C6C7=CC=C(C=[N]74)C)[N]8=CC=C(C=C8C=9C=C(C=C[N]95)C(F)(F)F)C(F)(F)F)C.[F-][P+5]([F-])([F-])([F-])([F-])[F-]
• InChI: InChI=1S/C12H6F6N2.2C12H8F2N.F6P.Ir/c13-11(14,15)7-1-3-19-9(5-7)10-6-8(2-4-20-10)12(16,17)18;2*1-8-2-5-12(15-7-8)10-4-3-9(13)6-11(10)14;1-7(2,3,4,5)6;/h1-6H;2*2-3,5-7H,1H3;;/q;3*-1;+3
• chave InChI: RYKRFKQFYGHADE-UHFFFAOYSA-N

Descrição

Aplicação

Under a dual catalytic copper/photoredox manifold, the Mes-Umemoto reagent has been demonstrated to be an excellent photocatalyst for the trifluoromethylation of alkyl halides and aryl halides to yield alkyl-CF₃ and aryl-CF₃ in high yields. In both cases, these reactions exhibit wide substrate scope with good functional group tolerance. More specifically, a variety of 5-membered and 6-membered heteroaryl halides can be readily converted to the corresponding trifluoromethylheteroarenes under mild conditions. For trifluoromethylation reactions, use with dMesSCF₃ (901466) and supersilanol (902489).

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

Outras notas

A radical approach to the copper oxidative addition problem:Trifluoromethylation of bromoarenes

Informações de segurança

• Código de classe de armazenamento: 11 - Combustible Solids
• Classe de risco de água (WGK): WGK 3
• Ponto de fulgor (°F): Not applicable
• Ponto de fulgor (°C): Not applicable