911607
[Ir(dFOMeppy)2-(5,5′-dCF3bpy)]PF6
≥95%
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About This Item
Fórmula empírica (Notação de Hill):
C36H22F16IrN4O2P
Número CAS:
Peso molecular:
1069.75
Código UNSPSC:
12161600
NACRES:
NA.22
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Ensaio
≥95%
Formulário
powder or crystals
adequação da reação
reaction type: Photocatalysis
reagent type: catalyst
pf
>300 °C
ativação do fotocatalisador
465 nm
Categorias relacionadas
Aplicação
[Ir(dFOMeppy)2-(5,5′-dCF3bpy)]PF6 is a versatile photocatalyst that can be used for a variety of synthetic transformations including the trifluoromethylation of alkyl bromides.
Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)
Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)
produto relacionado
Código de classe de armazenamento
11 - Combustible Solids
Classe de risco de água (WGK)
WGK 3
Ponto de fulgor (°F)
Not applicable
Ponto de fulgor (°C)
Not applicable
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David J P Kornfilt et al.
Journal of the American Chemical Society, 141(17), 6853-6858 (2019-04-16)
Copper oxidative addition into organohalides is a challenging two-electron process. In contrast, formal oxidative addition of copper to Csp2 carbon-bromine bonds can be accomplished by employing latent silyl radicals under photoredox conditions. This novel paradigm for copper oxidative addition has
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