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904767

Sigma-Aldrich

[Ru(phen)3]Cl2

≥95%

Sinônimo(s):

Dichlorotris(1,10-phenanthroline)ruthenium(II) chloride

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About This Item

Fórmula empírica (Notação de Hill):
C36H24Cl2N6Ru
Número CAS:
23570-43-6
Peso molecular:
712.59
Número MDL:
MFCD00061374
Código UNSPSC:
12352101
NACRES:
NA.22

Ensaio

≥95%

Formulário

powder or crystals

adequação da reação

core: ruthenium
reagent type: catalyst
reaction type: Photocatalysis

pf

>300 °C

cadeia de caracteres SMILES

[Ru+2]951([NH]%10=C%11C%12=[NH]9C=CC=C%12C=CC%11=CC=C%10)([NH]6=C7C8=[NH]5C=CC=C8C=CC7=CC=C6)[NH]2=C3C4=[NH]1C=CC=C4C=CC3=CC=C2.[Cl-].[Cl-]

InChI

1S/3C12H8N2.2ClH.Ru/c3*1-3-9-5-6-10-4-2-8-14-12(10)11(9)13-7-1;;;/h3*1-8H;2*1H;/q;;;;;+2/p-2

chave InChI

UWXWBVKIJZGXQL-UHFFFAOYSA-L

Categorias relacionadas

Aplicação

[Ru(phen)3]Cl2 is a cyclometalated ruthenium complex that can be used in visible light mediated photocatalytic organic transformations.

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

Outras notas

Photocatalysis Tech Spotlight

Visible-Light-Mediated Decarboxylative Radical Additions to Vinyl Boronic Esters: Rapid Access to -Amino Boronic Esters

Código de classe de armazenamento

11 - Combustible Solids

Classe de risco de água (WGK)

WGK 3

Ponto de fulgor (°F)

Not applicable

Ponto de fulgor (°C)

Not applicable

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Certificados de análise (COA)

Lot/Batch Number
MKCP6084
MKCN3490

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Tanmay Chatterjee et al.
The Journal of organic chemistry, 81(16), 6995-7000 (2016-06-22)
A simple and practical method for the synthesis of substituted oxazoles has been developed using readily available α-bromoketones and benzylamines by visible-light photocatalysis at room temperature. The process, which requires 1 mol % of [Ru(bpy)3]Cl2 photocatalyst with K3PO4 and CCl3Br
Chelsea A Huff et al.
The Journal of organic chemistry, 81(16), 6980-6987 (2016-06-18)
We report the development of a method for room-temperature C-H hydroxymethylation of heteroarenes. A key enabling advance in this work was achieved by implementing visible light photoredox catalysis that proved to be applicable to many classes of heteroarenes and tolerant
Adam Noble et al.
Angewandte Chemie (International ed. in English), 57(8), 2155-2159 (2018-01-10)
The synthesis of alkyl boronic esters by direct decarboxylative radical addition of carboxylic acids to vinyl boronic esters is described. The reaction proceeds under mild photoredox catalysis and involves an unprecedented single-electron reduction of an α-boryl radical intermediate to the
Jun Chen et al.
Chemical communications (Cambridge, England), 54(50), 6780-6783 (2018-02-06)
A visible light-driven photocatalytic generation of sulfonamidyl radicals, and application to intramolecular alkene hydroamination, has been accomplished, providing a mild and efficient approach to various functionalized isoxazolidines. The success of this protocol is based on the strategy of oxidative deprotonation

Global Trade Item Number

SKUGTIN
904767-250MG
904767-100MG

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