190500

tert-Butyldimethylsilyl chloride

reagent grade, 97%

• Sinônimo(s): tert-Butyl(chloro)dimethylsilane, tert-Butyldimethylchlorosilane, TBDMSCl
• Fórmula linear: (CH₃)₃CSi(CH₃)₂Cl
• Número CAS: 18162-48-6
• Peso molecular: 150.72
• Beilstein: 505999
• Número CE: 242-042-4
• Número MDL: MFCD00000501
• Código UNSPSC: 12352103
• ID de substância PubChem: 24851442
• NACRES: NA.22

Propriedades

• grau: reagent grade
• Nível de qualidade: 200
• Ensaio: 97%
• Formulário: solid
• p.e.: 125 °C (lit.)
• pf: 86-89 °C (lit.)
• cadeia de caracteres SMILES: CC(C)(C)[Si](C)(C)Cl
• InChI: 1S/C6H15ClSi/c1-6(2,3)8(4,5)7/h1-5H3
• chave InChI: BCNZYOJHNLTNEZ-UHFFFAOYSA-N

Descrição

Aplicação

tert-Butyldimethylsilyl chloride (TBDMSCl) is an organosilicon compound that can be used as a versatile protecting reagent for alcohols, amines, amides, and various carboxylic acids. It is also used in the preparation of isoxazoline N-oxides from α-bromonitroalkanes and olefins. TBDMSCl is used as a precursor that forms a silicon substrate for Ag/ZnO/graphene-based nanocomposites to form effective photocatalytic system for hydrogen production.

Informações de segurança

• Pictogramas: GHS02,GHS05,GHS09
• Palavra indicadora: Danger
• Frases de perigo: H228,H314,H411
• Declarações de precaução: P210 - P260 - P273 - P280 - P303 + P361 + P353 - P305 + P351 + P338 + P310
• Classificações de perigo: Aquatic Chronic 2 - Eye Dam. 1 - Flam. Sol. 1 - Skin Corr. 1A
• Código de classe de armazenamento: 4.1B - Flammable solid hazardous materials
• Classe de risco de água (WGK): WGK 2
• Ponto de fulgor (°F): 71.6 °F - closed cup
• Ponto de fulgor (°C): 22 °C - closed cup