923451

(PhMPhos)PdCl₂

complex with CH₂Cl₂

• 別名: 1-Diadamantylphosphino-1′-diphenylphosphinoferrocene palladium dichloride
• 実験式（ヒル表記法）: C₄₂H₄₈Cl₂FeP₂Pd
• CAS番号: 2768152-18-5
• 分子量: 847.95
• UNSPSCコード: 12352101
• NACRES: NA.21

特性

• 品質水準: 100
• 形状: powder
• 反応適合性: reagent type: catalyst; reaction type: Cross Couplings

詳細

アプリケーション

(PhMPhos)PdCl₂ is an unsymmetrical ferrocene-based Pd-catalyst. The MPhos series of ligands are unsymmetrical diphosphino-ferrocenes bearing a bulky adamantyl group. (PhMPhos)PdCl₂ can be used for a variety of cross-coupling transformations, including Suzuki coupling, C-P coupling, and Csp²-Csp³ coupling. Demonstrated Csp²-Csp³ couplings include Murahashi-Feringa Coupling (Alkyl-Li), Kumada-Corriu coupling (Alkyl-MgX), Negishi coupling (Alkyl-ZnX) and Suzuki–Miyaura coupling (Alkyl-B(OR₂)).

Learn more about MPhos ligands and catalysts

その他情報

Tunable Unsymmetrical Ferrocene Ligands Bearing a Bulky Di-1-adamantylphosphino Motif for Many Kinds of Csp²–Csp³ Couplings

安全性情報

• ピクトグラム: GHS08,GHS07
• シグナルワード: Warning
• 危険有害性情報: H315,H319,H351
• 注意書き: P202 - P264 - P280 - P302 + P352 - P305 + P351 + P338 - P308 + P313
• 危険有害性の分類: Carc. 2 - Eye Irrit. 2 - Skin Irrit. 2
• 保管分類コード: 11 - Combustible Solids
• WGK: WGK 3
• 引火点(°F): Not applicable
• 引火点(℃): Not applicable