923443

PhMPhos

• 別名: 1-Diadamantylphosphino-1′-diphenylphosphinoferrocene
• 実験式（ヒル表記法）: C₄₂H₄₈FeP₂
• 分子量: 670.62
• UNSPSCコード: 12352200
• NACRES: NA.21

特性

• 形状: powder
• 品質水準: 100
• 反応適合性: reagent type: catalyst; reaction type: Cross Couplings; reagent type: ligand
• 官能基: phosphine

詳細

アプリケーション

PhMPhos is an unsymmetrical ferrocene-based phosphine ligand. The MPhos series of ligands are unsymmetrical diphosphino-ferrocenes bearing a bulky adamantyl group. Pd catalysts containing PhMPhos can be used for a variety of cross-coupling transformations, including Suzuki coupling, C-P coupling, and Csp²-Csp³ coupling. Demonstrated Csp²-Csp³ couplings include Murahashi-Feringa Coupling (Alkyl-Li), Kumada-Corriu coupling (Alkyl-MgX), Negishi coupling (Alkyl-ZnX) and Suzuki–Miyaura coupling (Alkyl-B(OR₂)).

Learn more about MPhos ligands and catalysts

その他情報

Tunable Unsymmetrical Ferrocene Ligands Bearing a Bulky Di-1-adamantylphosphino Motif for Many Kinds of Csp²–Csp³ Couplings

安全性情報

• 保管分類コード: 11 - Combustible Solids
• WGK: WGK 3
• 引火点(°F): Not applicable
• 引火点(℃): Not applicable