463558

2,8,9-Trimethyl-2,5,8,9-tetraaza-1-phosphabicyclo[3.3.3]undecane

• Sinônimo(s): Verkade superbase
• Fórmula empírica (Notação de Hill): C₉H₂₁N₄P
• Número CAS: 120666-13-9
• Peso molecular: 216.26
• Beilstein: 4970285
• Número MDL: MFCD00269837
• Código UNSPSC: 12352005
• ID de substância PubChem: 24870079
• NACRES: NA.22

Propriedades

• pf: 110-115 °C (lit.)
• Nível de qualidade: 100
• cadeia de caracteres SMILES: CN1CCN2CCN(C)P1N(C)CC2
• InChI: 1S/C9H21N4P/c1-10-4-7-13-8-5-11(2)14(10)12(3)6-9-13/h4-9H2,1-3H3
• chave InChI: PCYSWBQHCWWSFW-UHFFFAOYSA-N

Descrição

Aplicação

2,8,9-Trimethyl-2,5,8,9-tetraaza-1-phosphabicyclo[3.3.3]undecane is involved as a reactant in:

• Studies of N-heterocyclic carbene ligand effects on metal hydride bond energies.
• Synthesis of heterogenous basic catalysts immobilized on SBA-15 silica.
• Protection / deprotection strategies for diazeniumdiolate chemistry.
• Encaging of the molecule to study the change in its catalytic ability.
• C-N coupling reactions.
• Derivative synthesis used as a promoter for aza and thia-Michael reaction and Strecker reaction.

Reactant involved in:

• Studies of N-heterocyclic carbene ligand effects on metal hydride bond energies
• Synthesis of heterogenous basic catalysts immobilized on SBA-15 silica
• Protection / deprotection strategies for diazeniumdiolate chemistry
• Encaging of the molecule to study change in its catalytic ability
• C-N coupling reactions
• Derivative synthesis used as a promoter for aza and thia-Michael reaction and Strecker reaction

Informações de segurança

• Código de classe de armazenamento: 11 - Combustible Solids
• Classe de risco de água (WGK): WGK 3
• Ponto de fulgor (°F): Not applicable
• Ponto de fulgor (°C): Not applicable
• Equipamento de proteção individual: Eyeshields, Gloves, type N95 (US)