901415

N-(tert-Butyl)-N-((ethoxycarbonothioyl)thio)-3,5-bis(trifluoromethyl)benzamide

• Synonim(y): Alexanian xanthylation reagent
• Wzór empiryczny (zapis Hilla): C₁₆H₁₇F₆NO₂S₂
• Numer CAS: 2022988-45-8
• Masa cząsteczkowa: 433.43
• Kod UNSPSC: 12352111
• NACRES: NA.22

Właściwości

• Postać: solid
• Poziom jakości: 100
• mp: 40-46 °C
• grupa funkcyjna: amine; fluoro
• temp. przechowywania: −20°C

Opis

Zastosowanie

As reported by the Alexanian. laboratory, this reagent is used for site-selective, intermolecular C-H xanthylation of alkanes, leading to the rapid diversification of otherwise inert C-H bonds. Once installed, the xanthate group provides direct access to diverse product analogues via several aliphatic C-H transformations, including halogenation, deuteration, vinylation, and hydroxylation. Product is best stored in foil-wrapped vials in the freezer when not in use; however, it can be weighed out on the bench without risk of decomposition. This product is offered collaboratively with UNC-Chapel Hill and Erik Alexanian.

Inne uwagi

C–H Xanthylation: A Synthetic Platform for Alkane Functionalization.

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Informacja o środkach bezpieczeństwa

• Kod klasy składowania: 11 - Combustible Solids
• Klasa zagrożenia wodnego (WGK): WGK 3
• Temperatura zapłonu (°F): Not applicable
• Temperatura zapłonu (°C): Not applicable