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Key Documents

746746

Sigma-Aldrich

Lithium hexafluorophosphate solution

greener alternative

in ethylene carbonate and diethyl carbonate, 1.0 M LiPF6 in EC/DEC=50/50 (v/v), battery grade

Sinônimo(s):

1.0 M LiPF6 EC/DEC=50/50 (v/v)

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About This Item

Fórmula linear:
LiPF6
Número MDL:
Código UNSPSC:
26111700
ID de substância PubChem:
NACRES:
NA.23

grau

battery grade

Nível de qualidade

forma

solution

características do produto alternativo mais ecológico

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

concentração

(1.0 M LiPF6 in EC/DEC)

Impurezas

<15 ppm H2O
<50 ppm HF

cor

APHA: <50

pb

130 °C

densidade

1.26 g/mL at 25 °C (lit.)

traços de ânion

chloride (Cl-): ≤1 ppm
sulfate (SO42-): ≤2 ppm

traços de cátion

Ca: ≤1 ppm
Fe: ≤1 ppm
K: ≤1 ppm
Na: ≤1 ppm
Pb: ≤1 ppm

aplicação(ões)

battery manufacturing

categoria alternativa mais ecológica

cadeia de caracteres SMILES

F[P-](F)(F)(F)(F)F.[Li+]

InChI

1S/F6P.Li/c1-7(2,3,4,5)6;/q-1;+1

chave InChI

AXPLOJNSKRXQPA-UHFFFAOYSA-N

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Descrição geral

Lithium hexafluorophosphate solution in ethylene carbonate and diethyl carbonate is a class of electrolytic solution that can be used in the fabrication of lithium-ion batteries. Lithium-ion batteries consist of anode, cathode, and electrolyte with a charge-discharge cycle. These materials enable the formation of greener and sustainable batteries for electrical energy storage.
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

Aplicação

LiPF6 EC/DMC is widely used as an electrolyte that is thermally stable in solvents. It can be mainly used in the fabrication of lithium-ion batteries.
Liquid electrolyte solutions play a key role in lithium ion batteries (LIB) acting as carrier of lithium ions between the cathode and anode. High purity and battery grade electrolyte solutions are thus crucial for lithium ion battery performance. The most common LIB electrolytes are derived from solutions of lithium salt, such as LiPF6 in non-aqueous solvents, example alkyl carbonates or solvent blend. The choice of the electrolyte solution is dependent on both the operating conditions like temperature and the nature of the electrode material in the LIB. The performance of the electrolyte solutions can be further modified with appropriate additives.
The ready-to-use electrolyte solutions are available in different solvent blends and can support a wide variety of lithium ion battery applications. These solutions are high purity and battery grade thus making them also suitable as standards in LIB research. Customized formulations can be made by inter-mixing the electrolyte solutions or by mixing appropriate of additives.

Outras notas

Handling instructions:
  • Do not use with glass equipment
  • All work should be done very quickly under dry air to prevent electrolytes from water uptake and solvent vaporization.

Informações legais

Product of MU Ionic Solutions Corp

Palavra indicadora

Danger

Classificações de perigo

Acute Tox. 4 Oral - Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT RE 1 Inhalation - STOT RE 2 Oral

Órgãos-alvo

Bone,Teeth, Kidney

Código de classe de armazenamento

3 - Flammable liquids

Classe de risco de água (WGK)

WGK 2

Ponto de fulgor (°F)

86.0 °F

Ponto de fulgor (°C)

30 °C


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Visite a Biblioteca de Documentos

Comparison of the thermal stability of lithiated graphite in LiBOB EC/DEC and in LiPF6 EC/DEC
Jiang J and Dahn JR
Electrochemical and Solid-State Letters, 6(9), A180-A180 (2003)
Reactivity of charged LiVPO4F with 1 M LiPF6 EC: DEC electrolyte at high temperature as studied by accelerating rate calorimetry
Zhou F, et al.
Electrochemical Communications, 11(3), 589-591 (2009)
Lucht, B. L.;
Energy Production and Storage, 333-333 (2010)
Visualization of electrode-electrolyte interfaces in LiPF6/EC/DEC electrolyte for lithium ion batteries via in situ TEM
Zeng Z, et al.
Nano Letters, 14(4), 1745-1750 (2014)
Lex-Balducci, A.;
Lithium-Ion Batteries, 147-147 (2012)

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The critical technical challenges associated with the commercialization of electric vehicle batteries include cost, performance, abuse tolerance, and lifespan.

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