Pular para o conteúdo
Merck
Todas as fotos(4)

Documentos Principais

Visualizar Toda a Documentação

517135

Sigma-Aldrich

Diethyl carbonate

greener alternative

anhydrous, ≥99%

Sinônimo(s):

Diatol, Eufin, H-DEC

Faça loginpara ver os preços organizacionais e de contrato
Todas as fotos(4)

About This Item

Fórmula linear:
(C2H5O)2CO
Número CAS:
105-58-8
Peso molecular:
118.13
Beilstein:
956591
Número CE:
203-311-1
Número MDL:
MFCD00009107
Código UNSPSC:
12352100
ID de substância PubChem:
24873944
NACRES:
NA.22

grau

anhydrous

densidade de vapor

4.1 (vs air)

pressão de vapor

10 mmHg ( 23.8 °C)
59 mmHg ( 37.8 °C)

Ensaio

≥99%

características do produto alternativo mais ecológico

Less Hazardous Chemical Syntheses
Safer Solvents and Auxiliaries
Design for Degradation
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

Impurezas

<0.002% water
<0.005% water (100 mL)

índice de refração

n20/D 1.384 (lit.)

p.e.

126-128 °C (lit.)

pf

−43 °C (lit.)

solubilidade

water: insoluble

densidade

0.975 g/mL at 25 °C (lit.)

grupo funcional

carbonate

categoria alternativa mais ecológica

Aligned,

cadeia de caracteres SMILES

O=C(OCC)OCC

InChI

1S/C5H10O3/c1-3-7-5(6)8-4-2/h3-4H2,1-2H3

chave InChI

OIFBSDVPJOWBCH-UHFFFAOYSA-N

Procurando produtos similares? Visita Guia de comparação de produtos

Descrição geral

Diethyl carbonate is an dialkylcarbonate. The synthesis of diethyl carbonate (DEC) from urea and ethanol has been investigated.
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product is used as a greener reagent. Click here for more information.

Aplicação

Diethyl carbonate may be used in the following studies:
  • Synthesis of β-enamino esters.
  • Synthesis of carbamates and unsymmetrical alkyl carbonates, via reaction with aliphatic amines or alcohols by using a hybrid organic-inorganic material prepared by anchoring TBD to MCM-41 silica.
  • As solvent in ruthenium catalyzed direct functionalisation of arene C-H bonds by aryl halides.
  • To compose the commercial liquid electrolyte for lithium ion batteries.
  • Homogeneous alkoxycarbonylation of cellulose.

Características e benefícios

Greener chemical

Pictogramas

Flame
GHS02

Palavra indicadora

Warning

Frases de perigo

H226

Declarações de precaução

P210 - P233 - P240 - P241 - P242 - P243

Classificações de perigo

Flam. Liq. 3

Código de classe de armazenamento

3 - Flammable liquids

Classe de risco de água (WGK)

WGK 1

Ponto de fulgor (°F)

77.0 °F - closed cup

Ponto de fulgor (°C)

25 °C - closed cup

Equipamento de proteção individual

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Escolha uma das versões mais recentes:

Certificados de análise (COA)

Lot/Batch Number
SHBN7328
SHBM9866
SHBL1343
SHBJ9214
SHBJ7647

Não está vendo a versão correta?

Se precisar de uma versão específica, você pode procurar um certificado específico pelo número do lote ou da remessa.

Pesquise por COA

Já possui este produto?

Encontre a documentação dos produtos que você adquiriu recentemente na biblioteca de documentos.

Visite a Biblioteca de Documentos

Os clientes também visualizaram

Slide 1 of 6

1 of 6

Ethylene carbonate battery grade, &#8805;99%, acid &lt;10 ppm, H2O &lt;10 ppm

Sigma-Aldrich

809950

Ethylene carbonate

Dimethyl carbonate ReagentPlus&#174;, 99%

Sigma-Aldrich

D152927

Dimethyl carbonate

Ethyl methyl carbonate battery grade, 99.9%, acid &lt;10 ppm, H2O &lt;10ppm

Sigma-Aldrich

809934

Ethyl methyl carbonate

Ethylene carbonate for synthesis

Sigma-Aldrich

8.44011

Ethylene carbonate

Dimethyl carbonate battery grade, &#8805;99.9%, acid &lt;10 ppm, H2O &lt;10 ppm

Sigma-Aldrich

809942

Dimethyl carbonate

Lithium hexafluorophosphate solution in ethylene carbonate and diethyl carbonate, 1.0 M LiPF6 in EC/DEC=50/50 (v/v), battery grade

Sigma-Aldrich

746746

Lithium hexafluorophosphate solution

Zhiyuan Zeng et al.
Faraday discussions, 176, 95-107 (2015-01-20)
We study the lithiation of a Au electrode in an electrochemical liquid cell using transmission electron microscopy (TEM). The commercial liquid electrolyte for lithium ion batteries (1 M lithium hexafluorophosphate LiPF6 dissolved in 1 : 1 (v/v) ethylene carbonate (EC) and diethyl
Diethyl carbonate as a solvent for ruthenium catalysed C-H bond functionalisation.
Arockiam P, et al.
Green Chemistry, 11(11), 1871-1875 (2009)
Synthesis of diethyl carbonate by catalytic alcoholysis of urea.
Wang D, et al.
Fuel Processing Technology, 88(8), 807-812 (2007)
Catalytic activity of MCM-41-TBD in the selective preparation of carbamates and unsymmetrical alkyl carbonates from diethyl carbonate.
Carloni S, et al.
J. Catal., 205(1), 199-204 (2002)
Sara R Labafzadeh et al.
ChemSusChem, 8(1), 77-81 (2014-11-08)
Dialkylcarbonates are viewed as low-cost, low-toxicity reagents, finding application in many areas of green chemistry. Homogeneous alkoxycarbonylation of cellulose was accomplished by applying dialkycarbonates (dimethyl and diethyl carbonate) in the ionic liquid-electrolyte trioctylphosphonium acetate ([P8881 ][OAc])/DMSO or 1-ethyl-3-methylimidazolium acetate ([emim][OAc]).
Exibir todos os documentos relacionados

Artigos

High-Energy Lithium-Ion Batteries via a Couette–Taylor-Flow-Reactor

Dr. Schmuch, Dr. Siozios, Professor Dr. Winter, and Dr. Placke review the challenges and opportunities of nickelrich layered oxide cathode materials. They discuss production processes for the layered oxide cathode materials as well as their chemistry and morphology.

Complex Hydrides: A New Category of Solid-state Lithium Fast-ion Conductors

Research and development of solid-state lithium fast-ion conductors is crucial because they can be potentially used as solid electrolytes in all-solid-state batteries, which may solve the safety and energy-density related issues of conventional lithium-ion batteries that use liquid (farmable organic) electrolytes.

Electrode Materials for Lithium Ion Batteries

Electrode Materials for Lithium Ion Batteries

Olivine-Type Cathode Materials for Lithium-Ion Batteries

Lithium-ion batteries (LIBs) have been widely adopted as the most promising portable energy source in electronic devices because of their high working voltage, high energy density, and good cyclic performance.

Ver tudo

Nossa equipe de cientistas tem experiência em todas as áreas de pesquisa, incluindo Life Sciences, ciência de materiais, síntese química, cromatografia, química analítica e muitas outras.

Entre em contato com a assistência técnica