About This Item
Fórmula linear:
CF3CH2SH
Número CAS:
Peso molecular:
116.11
Número MDL:
Código UNSPSC:
12352100
ID de substância PubChem:
NACRES:
NA.22
Produtos recomendados
pressão de vapor
7.85 psi ( 20 °C)
Ensaio
95%
forma
liquid
índice de refração
n20/D 1.352 (lit.)
pb
34-35 °C (lit.)
densidade
1.305 g/mL at 25 °C (lit.)
cadeia de caracteres SMILES
FC(F)(F)CS
InChI
1S/C2H3F3S/c3-2(4,5)1-6/h6H,1H2
chave InChI
RYRLLAOLJVDVNN-UHFFFAOYSA-N
Descrição geral
2,2,2-Trifluoroethanethiol is a fluorinated thiol. The microwave spectrum of 2,2,2-trifluoroethanethiol, and its deuterated species, CF3CH2SD has been studied. The gas phase acidity and basicity of 2,2,2-trifluoroethanethiol (TFET) has been investigated by Fourier transform ion cyclotron resonance spectroscopy. Reaction of 2,2,2-trifluoroethanethiol on Mo(110) surface was studied using temperature-programmed section, Auger electron and infrared spectroscopies.
2,2,2-Trifluoroethanethiol is basic in nature and forms charge transfer complexes with molecular iodine.
Aplicação
- Advancements in Peptide Synthesis: A novel synthesis of β-thiol phenylalanine showcases the use of 2,2,2-Trifluoroethanethiol in facilitating one-pot ligation-desulfurization chemistry. This technique is pivotal for developing new peptide-based pharmaceuticals, enhancing both the efficiency and versatility of peptide synthesis (Malins et al., 2015).
acessório
Nº do produto
Descrição
Preços
Palavra indicadora
Danger
Frases de perigo
Declarações de precaução
Classificações de perigo
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Flam. Liq. 1 - Skin Irrit. 2 - STOT SE 3
Órgãos-alvo
Respiratory system
Código de classe de armazenamento
3 - Flammable liquids
Classe de risco de água (WGK)
WGK 3
Ponto de fulgor (°F)
-11.2 °F - closed cup
Ponto de fulgor (°C)
-24 °C - closed cup
Equipamento de proteção individual
Eyeshields, Faceshields, Gloves
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Intrinsic (gas-phase) basicities and stability of charge-transfer complexes in solution.
Bouab W, et al.
Journal of Physical Organic Chemistry, 10(5), 343-346 (1997)
Effect of Fluorination on Thiol Reactivity: Reaction of 2, 2, 2-Trifluoroethanethiol on Mo (110).
Napier ME and Friend CM.
The Journal of Physical Chemistry, 99(21), 8750-8757 (1995)
Intrinsic acidity and basicity of 2, 2, 2-trifluoroethanethiol. The first experimental and theoretical study.
Molina MT, et al.
The Journal of Organic Chemistry, 61(16), 5485-5491 (1996)
Dong Min Sim et al.
ACS nano, 9(12), 12115-12123 (2015-10-28)
MoS2 is considered a promising two-dimensional active channel material for future nanoelectronics. However, the development of a facile, reliable, and controllable doping methodology is still critical for extending the applicability of MoS2. Here, we report surface charge transfer doping via
Harald Møllendal
The journal of physical chemistry. A, 112(32), 7481-7487 (2008-07-22)
The microwave spectrum of 2,2,2-trifluoroethanethiol, CF3CH2SH, and of one deuterated species, CF3CH2SD, has been investigated in the 7-80 GHz spectral interval. The microwave spectra of the ground and three vibrationally excited states belonging to three different normal modes of one
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