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Key Documents

167169

Sigma-Aldrich

3-Bromo-1-propanol

97%

Sinônimo(s):

Trimethylene bromohydrin

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About This Item

Fórmula linear:
Br(CH2)3OH
Número CAS:
Peso molecular:
138.99
Beilstein:
969160
Número CE:
Número MDL:
Código UNSPSC:
12352100
ID de substância PubChem:
NACRES:
NA.22

Ensaio

97%

forma

liquid

índice de refração

n20/D 1.488 (lit.)

pb

62 °C/5 mmHg (lit.)

densidade

1.537 g/mL at 25 °C (lit.)

grupo funcional

bromo

temperatura de armazenamento

2-8°C

cadeia de caracteres SMILES

OCCCBr

InChI

1S/C3H7BrO/c4-2-1-3-5/h5H,1-3H2

chave InChI

RQFUZUMFPRMVDX-UHFFFAOYSA-N

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Descrição geral

Reaction between 3-bromo-1-propanol, phenol and a series of phenols having substituents in 4-position has been studied in micellar media and in microemulsions based on cationic or a nonionic surfactant.

3-Bromo-1-propanol is an electrophile used as a substrate in nucleophilic substitution reactions and in the redox polymerization.

Aplicação

3-Bromo-1-propanol was used in the synthesis of fluorescent halide-sensitive quinolinium dyes and molten salt-polymers. It was used in the synthesis of chiral, quaternary prolines via cyclization of quaternary amino acids.
Recently used as a grafting agent in the synthesis of recyclable reagents for Swern oxidation

Pictogramas

CorrosionExclamation mark

Palavra indicadora

Danger

Frases de perigo

Classificações de perigo

Acute Tox. 4 Oral - Eye Dam. 1

Código de classe de armazenamento

10 - Combustible liquids

Classe de risco de água (WGK)

WGK 3

Ponto de fulgor (°F)

149.0 °F - closed cup

Ponto de fulgor (°C)

65 °C - closed cup

Equipamento de proteção individual

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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Fredrik Currie
Journal of colloid and interface science, 277(1), 230-234 (2004-07-28)
The reaction between 3-bromo-1-propanol and phenol and a series of phenols carrying substituents in 4-position was studied in micellar media and in microemulsions based on either a cationic or a nonionic surfactant. The reactivity and the yield were evaluated and
Takeo Kawabata et al.
Journal of the American Chemical Society, 128(48), 15394-15395 (2006-11-30)
An enantiodivergent asymmetric cyclization of N-Boc-N-omega-bromoalkyl-alpha-amino acid derivatives has been developed. With potassium amide bases in DMF, cyclization proceeds with retention of configuration, while inversion of configuration was observed with lithium amide bases in THF. Chirality of the parent amino
Wei Song et al.
Molecules (Basel, Switzerland), 25(17) (2020-08-23)
Azobenzene (AB) units were successfully introduced into poly(1,6-heptadiyne)s in order to ensure smooth synthesis of double- and single-stranded poly(1,6-heptadiyne)s (P1 and P2) and simultaneously realize the self-assembly by Grubbs-III catalyst-mediated metathesis cyclopolymerization (CP) of AB-functionalized bis(1,6-heptadiyne) and 1,6-heptadiyne monomers (M1
Synthesis of molten salt-type polymer brush and effect of brush structure on the ionic conductivity.
Yoshizawa M and Ohno H.
Electrochimica Acta, 46(10), 1723-1728 (2001)
C D Geddes et al.
Analytical biochemistry, 293(1), 60-66 (2001-05-25)
Three fluorescent halide-sensitive quinolinium dyes have been produced by the reaction of the 6-methylquinoline heterocyclic nitrogen base with methyl bromide, methyl iodide, and 3-bromo-1-propanol. The quaternary salts, unlike the precursor molecule, are readily water soluble and the fluorescence intensity of

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