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208523

Sigma-Aldrich

Ruthenium(III) chloride

Ru content 45-55%

Synonim(y):

Ruthenium trichloride

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About This Item

Wzór liniowy:
RuCl3
Numer CAS:
10049-08-8
Masa cząsteczkowa:
207.43
Numer WE:
233-167-5
Numer MDL:
MFCD00011208
Kod UNSPSC:
12161600
Identyfikator substancji w PubChem:
24852520
NACRES:
NA.22

Poziom jakości

200

Postać

solid

przydatność reakcji

core: ruthenium
reagent type: catalyst
reaction type: Atom Transfer Radical Polymerization (ATRP)

gęstość

3.11 g/mL at 25 °C (lit.)

ciąg SMILES

Cl[Ru](Cl)Cl

InChI

1S/3ClH.Ru/h3*1H;/q;;;+3/p-3

Klucz InChI

YBCAZPLXEGKKFM-UHFFFAOYSA-K

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Opis ogólny

Ruthenium(III) chloride is a chemical compound, that can be used as a mild Lewis acid catalyst for the acetalization of aldehydes, acetalization of alcohols, and conversion of ketoximes to amides. Additionally, it can also be used as a precursor to synthesize Ru nanoparticles.

Zastosowanie

Ruthenium(III) chloride is used as a catalyst:

  • In the synthesis of β‐amino alcohols by nucleophilic opening of epoxides with anilines.
  • In the acetylation of varies of phenols, alcohols, thiols, and amines under mild conditions.
  • In the synthesis of α‐aminonitriles by mixing aldehydes, amines, and trimethylsilyl cyanides.

Inne uwagi

insoluble form
This page may contain text that has been machine translated.

Hasło ostrzegawcze

Danger

Zwroty wskazujące rodzaj zagrożenia

H302,H314,H411

Klasyfikacja zagrożeń

Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Skin Corr. 1B

Kod klasy składowania

8B - Non-combustible corrosive hazardous materials

Klasa zagrożenia wodnego (WGK)

WGK 3

Temperatura zapłonu (°F)

Not applicable

Temperatura zapłonu (°C)

Not applicable

Środki ochrony indywidualnej

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

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Certyfikaty analizy (CoA)

Lot/Batch Number
MKCQ9411
MKCQ9412
MKCQ1043
MKCM5968
MKCM5969

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Dokumenty związane z niedawno zakupionymi produktami zostały zamieszczone w Bibliotece dokumentów.

Odwiedź Bibliotekę dokumentów

Patrik Västilä et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 12(12), 3218-3225 (2006-01-28)
We studied the role of alkali cations in the [{RuCl2(p-cymene)}2]-pseudo-dipeptide-catalyzed enantioselective transfer hydrogenation of ketones with isopropanol. Lithium salts were shown to increase the enantioselectivity of the reaction when iPrONa or iPrOK was used as the base. Similar transfer-hydrogenation systems
Tetrahedron Letters, 48, 5131-5131 (2007)
Yoshihiko Yamamoto et al.
Organic & biomolecular chemistry, 3(9), 1768-1775 (2005-04-29)
In the presence of catalytic amounts of Cp*RuCl(cod), the partially intramolecular cyclotrimerizations of various C-alkynylglycosides and C-diynylglycosides proceeded at ambient temperature to afford C-arylglycosides.
Jong Seok Lee et al.
The Journal of organic chemistry, 72(15), 5820-5823 (2007-06-26)
Ruthenium-catalyzed site-specific C-H oxyfunctionalization of steroidal ethers with periodate or bromate as terminal oxidants in phosphate buffer provided the acid-sensitive C-16 hydroxy compounds in high yields. Phosphate buffer (pH 7.5) significantly inhibits formation of unwanted side products generated under more
Sébastien Perdriau et al.
ChemSusChem, 5(12), 2427-2434 (2012-10-13)
Cardanol, a constituent of cashew nutshell liquid (CNSL), was subjected to transfer hydrogenation catalyzed by RuCl(3) using isopropanol as a reductant. The side chain of cardanol, which is a mixture of a triene, a diene, and a monoene, was selectively
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Protokoły

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