695157

ビス(3,5-ジメチルフェニル)ホスフィン

• 実験式（ヒル表記法）: C₁₆H₁₉P
• CAS番号: 71360-06-0
• 分子量: 242.30
• MDL番号: MFCD01074629
• UNSPSCコード: 12352103
• PubChem Substance ID: 329761721
• NACRES: NA.22

特性

• フォーム: liquid
• 品質水準: 100
• 反応適合性: reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling; reagent type: ligand
• 屈折率: n20/D 1.599
• 密度: 1.017 g/mL at 25 °C
• 官能基: phosphine
• SMILES記法: Cc1cc(C)cc(Pc2cc(C)cc(C)c2)c1
• InChI: 1S/C16H19P/c1-11-5-12(2)8-15(7-11)17-16-9-13(3)6-14(4)10-16/h5-10,17H,1-4H3
• InChI Key: GPFIUEZTNRNFGD-UHFFFAOYSA-N

詳細

アプリケーション

Bis(3,5-dimethylphenyl)phosphine can be used as a reactant to prepare:

• Iron(II) chiral diimine diphosphine complexes as catalysts for the asymmetric transfer hydrogenation of ketones.
• The complex of iridium with biphenol phosphite-phosphine bidentate ligand as an asymmetric catalyst for the hydrogenation of N-arylimines.
• Chiral phosphines with excellent stereoselectivity by 1, 4 addition reaction with α,β-unsaturated aldehydes using a palladium catalyst.

法的情報

Kanata Chemical Technologies, Inc.の製品です。

安全性情報

• ピクトグラム: GHS07
• シグナルワード: Warning
• 危険有害性情報: H302
• 危険有害性の分類: Acute Tox. 4 Oral
• 保管分類コード: 10 - Combustible liquids
• WGK: WGK 3
• 引火点(°F): >230.0 °F
• 引火点(℃): > 110 °C
• 個人用保護具 (PPE): Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter