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Merck
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Key Documents

E50604

Sigma-Aldrich

Ethyltriphenylphosphonium bromide

99%

Sinônimo(s):

TEP

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About This Item

Fórmula linear:
[(C6H5)3P+C2H5]Br-
Número CAS:
Peso molecular:
371.25
Beilstein:
3599630
Número CE:
Número MDL:
Código UNSPSC:
12352002
ID de substância PubChem:
NACRES:
NA.22

Nível de qualidade

Ensaio

99%

adequação da reação

reaction type: C-C Bond Formation

pf

203-205 °C (lit.)

cadeia de caracteres SMILES

[Br-].CC[P+](c1ccccc1)(c2ccccc2)c3ccccc3

InChI

1S/C20H20P.BrH/c1-2-21(18-12-6-3-7-13-18,19-14-8-4-9-15-19)20-16-10-5-11-17-20;/h3-17H,2H2,1H3;1H/q+1;/p-1

chave InChI

JHYNXXDQQHTCHJ-UHFFFAOYSA-M

Procurando produtos similares? Visita Guia de comparação de produtos

Aplicação

Reactant for synthesis of:
  • D-amino acids from L-cysteine-derived thiazolidines
  • Leiodolide A via aldol reactions and Horner-Wadsworth-Emmons olefination
  • Cycloalkanoindolines via diastereoselective intramolecular inimo-ene reactions
  • WXYZA′ domain of maitotoxin using the coupling of key building blocks

Reactant for:
  • Solid-state metathesis polycondensation to form alkyl-dipropenylthiophene monomers
  • Mizoroki-Heck cyclization and cascading Tsuji-Trost cyclization / lactonization cyclization reactions for synthesis of an ABC ring system

Pictogramas

CorrosionSkull and crossbones

Palavra indicadora

Danger

Frases de perigo

Classificações de perigo

Acute Tox. 3 Oral - Aquatic Chronic 3 - Eye Dam. 1

Código de classe de armazenamento

6.1D - Non-combustible, acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

Classe de risco de água (WGK)

WGK 2

Ponto de fulgor (°F)

401.0 °F

Ponto de fulgor (°C)

205 °C

Equipamento de proteção individual

dust mask type N95 (US), Eyeshields, Faceshields, Gloves


Certificados de análise (COA)

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Yoshihiro Noda et al.
Aging, 9(2), 556-572 (2017-02-18)
Gamma-aminobutyric acid (GABA)ergic and glutamatergic neurotransmissions in the prefrontal cortex decreases with age. Further, cognitive function mediated through the dorsolateral prefrontal cortex (DLPFC) also declines with age. Although neuroimaging studies have demonstrated decreased levels of these substances, direct neurophysiological data
Airat Gubaev et al.
Nucleic acids research, 44(21), 10354-10366 (2016-08-26)
The topological state of DNA is important for replication, recombination and transcription, and is regulated in vivo by DNA topoisomerases. Gyrase introduces negative supercoils into DNA at the expense of ATP hydrolysis. It is the accepted view that gyrase achieves
Chris M Wood et al.
The Journal of experimental biology, 219(Pt 20), 3218-3226 (2016-11-02)
Nitrogen (N) appears to be a limiting dietary resource for elasmobranchs, required not only for protein growth but also for urea-based osmoregulation. Building on recent evidence that the toxicant ammonia can be taken up actively at the gills of the
Rafał Oliwa
Materials (Basel, Switzerland), 13(17) (2020-08-28)
We investigated the effect of modified aluminosilicates, including bentonite from Armenia (BA) modified with quaternary ammonium salts (BAQAS) and phosphonium salts (BAQPS), on the mechanical properties and morphology of Kevlar/epoxy composites. The Kevlar/epoxy composites containing 1.0 or 3.0 wt.% modified
Yoshihiro Noda et al.
Depression and anxiety, 35(5), 448-456 (2018-04-11)
Dysfunctional neuroplasticity may be one of the pathophysiological mechanisms underlying major depression. We have previously established methods to assess neuroplasticity from the dorsolateral prefrontal cortex (DLPFC) using a paired associative stimulation (PAS) paradigm, which pairs a preceding peripheral nerve stimulation

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