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D105937

Sigma-Aldrich

1,2-Dihydronaphthalene

95%

Sinônimo(s):

1,2-Dialin, 3,4-Dihydronaphthalene

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About This Item

Fórmula empírica (Notação de Hill):
C10H10
Número CAS:
447-53-0
Peso molecular:
130.19
Beilstein:
1851372
Número CE:
207-183-8
Número MDL:
MFCD00001672
Código UNSPSC:
12352100
ID de substância PubChem:
24893339
NACRES:
NA.22

Ensaio

≥94.5% (GC)
95%

Formulário

liquid

índice de refração

n20/D 1.582 (lit.)

p.e.

89 °C/16 mmHg (lit.)

pf

−8 °C (lit.)

densidade

0.997 g/mL at 25 °C (lit.)

cadeia de caracteres SMILES

C1Cc2ccccc2C=C1

InChI

1S/C10H10/c1-2-6-10-8-4-3-7-9(10)5-1/h1-3,5-7H,4,8H2

chave InChI

KEIFWROAQVVDBN-UHFFFAOYSA-N

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Categorias relacionadas

Código de classe de armazenamento

10 - Combustible liquids

Classe de risco de água (WGK)

WGK 3

Ponto de fulgor (°F)

152.6 °F - closed cup

Ponto de fulgor (°C)

67 °C - closed cup

Equipamento de proteção individual

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

Escolha uma das versões mais recentes:

Certificados de análise (COA)

Lot/Batch Number
BCBQ3661V
BCBQ0980V
1452234V
1452234
1322202

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Sigma-Aldrich

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S L Eaton et al.
Applied and environmental microbiology, 62(12), 4388-4394 (1996-12-01)
The substrate oxidation profiles of Sphingomonas yanoikuyae B1 biphenyl-2,3-dioxygenase and cis-biphenyl dihydrodiol dehydrogenase activities were examined with 1,2-dihydronaphthalene and various cis-diols as substrates. m-Xylene-induced cells of strain B1 oxidized 1,2-dihydronaphthalene to (-)-(1R,2S)-cis-1,2-dihydroxy-1,2-3,4-tetrahydronaphthalene as the major product (73% relative yield). Small
Keith Smith et al.
Chemical communications (Cambridge, England), (8)(8), 886-887 (2002-07-19)
We have successfully prepared an unsymmetrical analogue of a Katsuki-type salen ligand having a single hydroxyalkyl group at its 6-position, and also its Mn(III) complex; attachment of the complex to a polymer gives a highly enantioselective and recoverable catalyst for
Tian-Yu Liu et al.
Chemical communications (Cambridge, England), (22)(22), 2228-2230 (2007-05-31)
The asymmetric Michael-type Friedel-Crafts reaction of naphthols and nitroolefins promoted by bifunctional thiourea-tertiary amine organocatalysts (up to 95% ee) was investigated; on simply extending the reaction time further cascade reactions could occur to generate enantiopure dimeric tricyclic 1,2-dihydronaphtho[2,1-b]furanyl-2-hydroxylamine derivatives.
Luiz F Silvia et al.
Molecules (Basel, Switzerland), 10(11), 1419-1428 (2007-11-17)
The oxidation of 2-(3,4-dihydronaphthalen-1-yl)-ethanol (1) with a variety of thallium(III) salts was investigated. An indan, formed by a ring contraction reaction, was obtained in good to moderate yields under a variety of reaction conditions: i) thallium triacetate (TTA) in aqueous
D S Torok et al.
Journal of bacteriology, 177(20), 5799-5805 (1995-10-01)
Bacterial strains expressing toluene and naphthalene dioxygenase were used to examine the sequence of reactions involved in the oxidation of 1,2-dihydronaphthalene. Toluene dioxygenase of Pseudomonas putida F39/D oxidizes 1,2-dihydronaphthalene to (+)-cis-(1S,2R)-dihydroxy-1,2,3,4-tetrahydronaphthalene, (+)-(1R)-hydroxy-1,2-dihydronaphthalene, and (+)-cis-(1R,2S)-dihydroxy-1,2-dihydronaphthalene. In contrast, naphthalene dioxygenase of Pseudomonas
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