B56404
4′-Bromoacetophenone
98%
Sinônimo(s):
1-Acetyl-4-bromobenzene
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About This Item
Fórmula linear:
BrC6H4COCH3
Número CAS:
Peso molecular:
199.04
Beilstein:
386015
Número CE:
Número MDL:
Código UNSPSC:
12352100
ID de substância PubChem:
NACRES:
NA.22
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Nível de qualidade
Ensaio
98%
Formulário
solid
p.e.
255 °C (lit.)
pf
49-51 °C (lit.)
cadeia de caracteres SMILES
CC(=O)c1ccc(Br)cc1
InChI
1S/C8H7BrO/c1-6(10)7-2-4-8(9)5-3-7/h2-5H,1H3
chave InChI
WYECURVXVYPVAT-UHFFFAOYSA-N
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Descrição geral
4′-Bromoacetophenone is used as an organic building block in Heck and Suzuki coupling reactions. Generates phenyl radicals upon UV irradiation.
Palavra indicadora
Warning
Frases de perigo
Declarações de precaução
Classificações de perigo
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Órgãos-alvo
Respiratory system
Código de classe de armazenamento
11 - Combustible Solids
Classe de risco de água (WGK)
WGK 3
Ponto de fulgor (°F)
>212.0 °F
Ponto de fulgor (°C)
> 100 °C
Equipamento de proteção individual
dust mask type N95 (US), Eyeshields, Faceshields, Gloves
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Gagan Chouhan et al.
Chemical communications (Cambridge, England), (45)(45), 4809-4811 (2007-11-16)
Magnetic nanoparticle-supported proline ligand was prepared and used for the CuI catalyzed Ullmann-type coupling reactions of aryl/heteroaryl bromides with various nitrogen heterocycles to form the corresponding N-aryl products in good to excellent yields; furthermore, this magnetic nanoparticle-supported proline ligand could
R Jeon et al.
Archives of pharmacal research, 24(1), 39-43 (2001-03-10)
4'-Bromoacetophenone analogs, which are able to generate monophenyl radicals capable of hydrogen atom abstraction, were investigated as possible photoinducible DNA cleaving agents. The potential of 4'-bromoacetophenone as a possible new DNA cleaver is explored. Pyrrolecarboxatmid conjugated 4'-bromoacetophenones, in particular, DNA
Mechanochemical solid-state Suzuki reactions using an in situ generated base.
Franziska Schneider et al.
ChemSusChem, 1(7), 622-625 (2008-08-15)
In vitro histamine release from basophils of asthmatic and atopic individuals in D2O.
R Tung et al.
Journal of immunology (Baltimore, Md. : 1950), 128(5), 2067-2072 (1982-05-01)
Lidiane S Araújo et al.
Marine drugs, 9(5), 889-905 (2011-06-16)
Several microorganisms were isolated from soil/sediment samples of Antarctic Peninsula. The enrichment technique using (RS)-1-(phenyl)ethanol as a carbon source allowed us to isolate 232 psychrophile/psychrotroph microorganisms. We also evaluated the enzyme activity (oxidoreductases) for enantioselective oxidation reactions, by using derivatives
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