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Key Documents

B56501

Sigma-Aldrich

4-Bromoanisole

≥99.0%

Sinônimo(s):

1-Bromo-4-methoxybenzene

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About This Item

Fórmula linear:
BrC6H4OCH3
Número CAS:
Peso molecular:
187.03
Beilstein:
1237590
Número CE:
Número MDL:
Código UNSPSC:
12352100
ID de substância PubChem:
NACRES:
NA.22

Nível de qualidade

Ensaio

≥99.0%

forma

liquid

índice de refração

n20/D 1.564 (lit.)

pb

223 °C (lit.)

pf

9-10 °C (lit.)

densidade

1.494 g/mL at 25 °C (lit.)

cadeia de caracteres SMILES

COc1ccc(Br)cc1

InChI

1S/C7H7BrO/c1-9-7-4-2-6(8)3-5-7/h2-5H,1H3

chave InChI

QJPJQTDYNZXKQF-UHFFFAOYSA-N

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Descrição geral

4-Bromoanisole is a useful brominating reagent. It is formed as reaction product in the reaction between HOBr and anisole. Suzuki coupling of 4-bromoanisole with phenylboronic acid catalyzed by palladium pincer complexes has been studied. Heck Reaction of 4-bromoanisole with ethyl acrylates in room-temperature ionic liquids is reported to afford ethyl 4-methoxycinnamate.

Aplicação

4-Bromoanisole was used in the synthesis of aryl 1,3-diketones.

Pictogramas

Exclamation mark

Palavra indicadora

Warning

Frases de perigo

Classificações de perigo

Acute Tox. 4 Oral - Skin Irrit. 2

Código de classe de armazenamento

10 - Combustible liquids

Classe de risco de água (WGK)

WGK 2

Ponto de fulgor (°F)

201.2 °F

Ponto de fulgor (°C)

94 °C

Equipamento de proteção individual

Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)


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New. J. Chem., 24(10), 745-747 (2000)
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Artigos

The Heck reaction is the palladium catalyzed cross-coupling reaction between alkenes and aryl or vinyl halides (or triflates) to afford substituted alkenes.

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