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Key Documents

449504

Sigma-Aldrich

Bis(trifluorometano)sulfonimida

Sinônimo(s):

Bis(trifluorometilsulfonil)amina, Bistrifluorometanossulfonimidato de lítio

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About This Item

Fórmula linear:
CF3SO2NLiSO2CF3
Número CAS:
Peso molecular:
287.09
Beilstein:
6625414
Número CE:
Número MDL:
Código UNSPSC:
12352302
ID de substância PubChem:
NACRES:
NA.22

pf

234-238 °C (lit.)

cadeia de caracteres SMILES

[Li]N(S(=O)(=O)C(F)(F)F)S(=O)(=O)C(F)(F)F

InChI

1S/C2F6NO4S2.Li/c3-1(4,5)14(10,11)9-15(12,13)2(6,7)8;/q-1;+1

chave InChI

QSZMZKBZAYQGRS-UHFFFAOYSA-N

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Aplicação

Bis(trifluoromethane)sulfonimide lithium salt (Li-TFSI) can be used:
  • As a chemical additive for improving the power conversion efficiencies in porphyrin-based organic solar cells.     
  • As a reagent in the preparation of imidazolium core bearing monomer ionic liquids to develop polymerized ionic liquids.
  • For the preparation of a chiral imidazolium salt via anion metathesis of the corresponding triflate.       
  • In the synthesis of solid polymer electrolytes for lithium-ion batteries. 
  • In the synthesis of polyelectrolyte reusable homogenous catalysts, which are used in the Diels–Alder reactions between isoprene and a variety of dienophiles.
  • Used in the preparation of electrolytes for lithium batteries and novel rare-earth Lewis acid catalysts.

Outras notas

For a review on fluorine containing nitrogen acids, see Coordination Chemistry Reviews.

Palavra indicadora

Danger

Classificações de perigo

Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Aquatic Chronic 3 - Eye Dam. 1 - Skin Corr. 1B - STOT RE 2 Oral

Órgãos-alvo

Nervous system

Código de classe de armazenamento

6.1B - Non-combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

Classe de risco de água (WGK)

WGK 3

Ponto de fulgor (°F)

Not applicable

Ponto de fulgor (°C)

Not applicable

Equipamento de proteção individual

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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13th ACS Winter Fluorine Conference, paper No. 8, January (1997)
Poly (ethylene oxide carbonates) solid polymer electrolytes for lithium batteries
Meabe L, et al.
Electrochimica Acta, 264, 367-375 (2018)
Tetrahedron Letters, 45, 4429-4429 (2004)
Electrochimica Acta, 41, 2369-2369 (1996)
Amino alcohol-derived chiral ionic liquids: structural investigations toward chiral recognition
Vasiloiu M, et al.
Tetrahedron Asymmetry, 26(18-19), 1069-1082 (2015)

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