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Key Documents

238325

Sigma-Aldrich

Allyl iodide

98%

Sinônimo(s):

3-Iodo-1-propene

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About This Item

Fórmula linear:
CH2=CHCH2I
Número CAS:
Peso molecular:
167.98
Beilstein:
1697594
Número CE:
Número MDL:
Código UNSPSC:
12352100
ID de substância PubChem:
NACRES:
NA.22

Nível de qualidade

Ensaio

98%

forma

liquid

contém

copper as stabilizer

índice de refração

n20/D 1.554 (lit.)

pb

102-103 °C (lit.)

solubilidade

alcohol: miscible(lit.)
chloroform: miscible(lit.)
diethyl ether: miscible(lit.)
water: insoluble (practically)(lit.)

densidade

1.837 g/mL at 25 °C (lit.)

grupo funcional

alkyl halide
iodo

temperatura de armazenamento

2-8°C

cadeia de caracteres SMILES

ICC=C

InChI

1S/C3H5I/c1-2-3-4/h2H,1,3H2

chave InChI

HFEHLDPGIKPNKL-UHFFFAOYSA-N

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Descrição geral

The interaction of allyl iodide with MoO3, Bi2O3 and molybdates of Bi, Co and Mg has been studied in the temperature range of 270-480°C.

Aplicação

Allyl iodide has been employed as:
  • precursor for generation of allyl radicals to study their recombination in a single pulse shock tube with gas chromatographic measurements
  • reagent used with allylindium sesquiiodide in the cis-double allylation of cyclopropenes

Palavra indicadora

Danger

Frases de perigo

Classificações de perigo

Acute Tox. 2 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B

Código de classe de armazenamento

3 - Flammable liquids

Classe de risco de água (WGK)

WGK 1

Ponto de fulgor (°F)

60.8 °F - closed cup

Ponto de fulgor (°C)

16 °C - closed cup

Equipamento de proteção individual

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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Interaction of allyl iodide with molybdate catalysts for the selective oxidation of hydrocarbons.
Grzybowska B, et al.
J. Catal., 49(2), 150-163 (1977)
Aleksandr Fridlyand et al.
The journal of physical chemistry. A, 117(23), 4762-4776 (2013-05-18)
The recombination and disproportionation of allyl radicals has been studied in a single pulse shock tube with gas chromatographic measurements at 1-10 bar, 650-1300 K, and 1.4-2 ms reaction times. 1,5-Hexadiene and allyl iodide were used as precursors. Simulation of
Tsunehisa Hirashita et al.
Organic & biomolecular chemistry, 5(13), 2154-2158 (2007-06-22)
The successive double allylation of cyclopropenes with allylindium sesquiiodide and allyl iodide proceeded with a cis-addition mode in the presence of other organometallics (e.g. Grignard reagent, cuprate, Et(2)Zn and Et(3)Al), giving the corresponding cis-diallylcyclopropanes in high yields.
Xin Ma et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 25(25), 6355-6361 (2019-02-28)
Unexpectedly, the 5-dehydroquinoline radical cation was formed in the gas phase from the 5-iodo-8-nitroquinolinium cation upon ion-trap collision-activated dissociation. This reaction involves the cleavage of a nitro group to generate an intermediate monoradical, namely, the 8-dehydro-5-iodoquinolinium cation, followed by rearrangement
Michael Lesslie et al.
European journal of mass spectrometry (Chichester, England), 21(3), 589-597 (2015-08-27)
Radical migration, both intramolecular and intermolecular, from the tyrosine phenoxyl radical Tyr(O(∙)) to the cysteine radical Cys(S(∙)) in model peptide systems was observed in the gas phase. Ion-molecule reactions (IMRs) between the radical cation of homotyrosine and propyl thiol resulted

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