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Key Documents

227722

Sigma-Aldrich

Silver hexafluorophosphate

98%

Sinônimo(s):

Silver(I) hexafluorophosphate

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About This Item

Fórmula linear:
AgPF6
Número CAS:
Peso molecular:
252.83
Número CE:
Número MDL:
Código UNSPSC:
12161600
ID de substância PubChem:
NACRES:
NA.22

Ensaio

98%

forma

solid

adequação da reação

core: silver
reagent type: catalyst

pf

102 °C (dec.) (lit.)

cadeia de caracteres SMILES

[Ag+].F[P-](F)(F)(F)(F)F

InChI

1S/Ag.F6P/c;1-7(2,3,4,5)6/q+1;-1

chave InChI

SCQBROMTFBBDHF-UHFFFAOYSA-N

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Descrição geral

Silver hexafluorophosphate can be used as a catalyst for the sulfimidation, hydrogenation of aldehydes to alcohols, and hydroacyloxylation of alkynes with carboxylic acids.

Aplicação

Used to prepare silver 3,3′-dicyanodiphenylacetylene coordination networks for study of the effect of ligands on network structure toward the goal of engineering novel materials. Preparation of supramolecular networks of Ag(I) complexes.

Pictogramas

Corrosion

Palavra indicadora

Danger

Frases de perigo

Classificações de perigo

Eye Dam. 1 - Skin Corr. 1B

Código de classe de armazenamento

8A - Combustible corrosive hazardous materials

Classe de risco de água (WGK)

WGK 3

Ponto de fulgor (°F)

Not applicable

Ponto de fulgor (°C)

Not applicable

Equipamento de proteção individual

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


Certificados de análise (COA)

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Visite a Biblioteca de Documentos

Silver-Catalyzed Hydrogenation of Aldehydes in Water
Jia Z, et al.
Angewandte Chemie (International Edition in English), 52, 11871-11874 (2013)
Journal of Organometallic Chemistry, 692, 4093-4093 (2007)
Gold (I)-catalyzed addition of carboxylic acids to alkynes
Chary B, et al.
The Journal of Organic Chemistry, 75, 7928-7931 (2010)
Keith A. Hirsch et al.
Inorganic chemistry, 36(14), 2960-2968 (1997-07-02)
Coordination networks of 3,3'-dicyanodiphenylacetylene (3,3'-DCPA, 1) with silver(I) salts characterized by single-crystal X-ray analysis are described. Network topology is found to depend on both the counterion and solvent employed during crystallization. The conformation adopted by the ligand varies between planar

Artigos

The importance of selectively fluorinating compounds in medicinal chemistry, biology, and organic synthesis is well appreciated and provides a major impetus to the discovery of new and mild fluorinating agents that can operate safely and efficiently.

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