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Documentos Principais

206075

Sigma-Aldrich

Potassium tetrachloroplatinate(II)

98%

Sinônimo(s):

Potassium platinum(II) chloride

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About This Item

Fórmula linear:
K2PtCl4
Número CAS:
Peso molecular:
415.09
Número CE:
Número MDL:
Código UNSPSC:
12352302
ID de substância PubChem:
NACRES:
NA.23

grau

for analytical purposes

Ensaio

98%

Formulário

solid

densidade

3.38 g/mL at 25 °C (lit.)

cadeia de caracteres SMILES

[K+].[K+].Cl[Pt--](Cl)(Cl)Cl

InChI

1S/4ClH.2K.Pt/h4*1H;;;/q;;;;2*+1;+2/p-4

chave InChI

RVRDLMCWUILSAH-UHFFFAOYSA-J

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Descrição geral

Potassium tetrachloroplatinate(II) is a ruby-red crystalline solid and can be prepared by reacting potassium hexachloroplatinate(IV) with cuprous chloride. It is mainly used as a reagent and inorganic catalyst in various chemical reactions. Its application includes the synthesis of other platinum compounds, organic transformations, and electroplating of metals. It is also a potential antitumor agent.

Aplicação

Potassium tetrachloroplatinate(II) can be used as:
  • A precursor to synthesize CO-tolerant catalyst for hydrogen-air fuel cells.
  • An active and stable catalyst for selective methane oxidation.
  • As a starting material to synthesize high-performance Pt-based phosphorescent materials for electroluminescent devices.

Características e benefícios

Reacts with bis(dithiolates) to form metal-bis(dithiolates) with applications in laser Q-switch materials, liquid crystals, optical CD recording media, bar code materials and superconductivity. Reacts with capping polymers to form shape-control colloidal platinum nanoparticles for catalysis and photocatalysts.

Palavra indicadora

Danger

Frases de perigo

Classificações de perigo

Acute Tox. 3 Oral - Eye Dam. 1 - Resp. Sens. 1 - Skin Irrit. 2 - Skin Sens. 1

Código de classe de armazenamento

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

Classe de risco de água (WGK)

WGK 1

Ponto de fulgor (°F)

Not applicable

Ponto de fulgor (°C)

Not applicable

Equipamento de proteção individual

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges


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Kyubin Shim et al.
Scientific reports, 9(1), 894-894 (2019-01-31)
Bimetallic nanoparticles (NPs) have aroused interest in various fields because of their synergetic and unique properties. Among those nanoparticles, we strategically approached and synthesized Au@Pt NPs via the sonochemical method with different molar ratios (e.g. 3:7, 5:5, and 7:3) of
Raj G
Advances in Inorganic Chemistry null
A Solution Phase Synthesis of Dendritic Platinum Nanoelectrocatalysts with the Assistance of Polyoxyethylene Nonylphenyl Ether.
Wang H, et al.
Journal of Inorganic and Organometallic Polymers and Materials, 25(2), 245-250 (2015)
Synthesis of shaped Pt nanoparticles using common anions or small molecules as shape-directing agents: observation of a strong halide or pseudo-halide effect.
Michel JA, et al.
Journal of Materials Chemistry, 3(5), 2012-2018 (2015)
The Biological Activity of Zeise's Salt and its Derivatives
Meieranz S, et al.
Angewandte Chemie (International Edition in English), 54(9), 2834-2837 (2015)

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