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184462

Sigma-Aldrich

Butyl chloroformate

98%

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About This Item

Fórmula linear:
ClCOOCH2CH2CH2CH3
Número CAS:
592-34-7
Peso molecular:
136.58
Beilstein:
605635
Número CE:
209-750-5
Número MDL:
MFCD00000650
Código UNSPSC:
12352100
ID de substância PubChem:
24851117
NACRES:
NA.22

pressão de vapor

2.42 psi ( 20 °C)

Nível de qualidade

100

Ensaio

98%

forma

liquid

índice de refração

n20/D 1.412 (lit.)

pb

142 °C (lit.)

densidade

1.074 g/mL at 25 °C (lit.)

temperatura de armazenamento

2-8°C

cadeia de caracteres SMILES

CCCCOC(Cl)=O

InChI

1S/C5H9ClO2/c1-2-3-4-8-5(6)7/h2-4H2,1H3

chave InChI

NRDQFWXVTPZZAZ-UHFFFAOYSA-N

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Categorias relacionadas

Aplicação

  • Butyl chloroformate was used in the synthesis of dextran alkyl carbonates.
  • It was also used in the synthesis of S-tert-alkyl-N,N-alkoxycarbonylmethyl-dithiocarbamate, radical polymerization with reversible addition-fragmentation chain transfer agent.
  • It was used as derivatization reagent in determination of linsidomine in plasma using high-performance liquid chromatographic separation with tandem mass spectrometric detection.

Palavra indicadora

Danger

Frases de perigo

H226 - H314 - H331

Classificações de perigo

Acute Tox. 3 Inhalation - Flam. Liq. 3 - Skin Corr. 1B

Código de classe de armazenamento

3 - Flammable liquids

Classe de risco de água (WGK)

WGK 1

Ponto de fulgor (°F)

100.4 °F - closed cup

Ponto de fulgor (°C)

38 °C - closed cup

Equipamento de proteção individual

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

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Sigma-Aldrich

237906

Phenyl chloroformate

Triisopropyl borate ≥98%

Sigma-Aldrich

197335

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F C Sutherland et al.
Journal of pharmaceutical and biomedical analysis, 22(3), 461-467 (2000-04-15)
A sensitive method for the determination of linsidomine in plasma was developed, using high-performance liquid chromatographic (HPLC) separation with tandem mass spectrometric detection. Linsidomine was derivatised with propyl chloroformate and extracted with tert-butyl methyl ether/1,2-dichloroethane (55:45, v/v), back-extracted into HCl
Multiblock copolymer synthesis via controlled radical polymerization in aqueous dispersions. Part 1: Synthesis of S-tert-alkyl-N,N-alkoxycarbonylmethyl-dithiocarbamate.
Bussels R and Koning CE.
Tetrahedron, 61(5), 1167-1174 (2005)
Andrea Y Garzón-Serrano et al.
Journal of forensic sciences, 65(4), 1085-1093 (2020-03-17)
Ammonium nitrate fuel oil is an explosive mixture found in most antipersonnel landmines (APL) buried throughout the Colombian territory. During more than 50 years of internal conflict, the Colombian government has found that trained dogs are the most effective method to
Tomáš Hložek et al.
Journal of analytical toxicology, 40(9), 749-753 (2016-09-04)
A simple, sensitive and robust method for simultaneous determination of antiepileptic drugs (gabapentin, pregabalin and vigabatrin) in human serum using GC-MS was developed and validated for clinical toxicology purposes. This method employs an emerging class of derivatization agents - alkyl
Thomas Elschner et al.
Carbohydrate polymers, 93(1), 216-223 (2013-03-08)
Dextran alkyl carbonates were synthesized applying ethyl chloroformate, butyl chloroformate, butyl fluoroformate and 1H-imidazole-1-carboxylates. The influence of the reaction conditions on the reaction efficiency and the substitution pattern was studied in detail. The structure of the products obtained was clearly
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