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167185

Sigma-Aldrich

Methyl 2-bromopropionate

98%

Sinônimo(s):

(±)-2-Bromopropionic acid methyl ester, (±)-Methyl 2-bromopropionate, 2-Bromopropanoic acid methyl ester, 2-Bromopropionic acid methyl ester, Methyl (±)-α-bromopropionate

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About This Item

Fórmula linear:
CH3CHBrCO2CH3
Número CAS:
5445-17-0
Peso molecular:
167.00
Beilstein:
1720592
Número CE:
226-642-3
Número MDL:
MFCD00000143
Código UNSPSC:
12352100
ID de substância PubChem:
24850199
NACRES:
NA.22

Ensaio

98%

Formulário

liquid

índice de refração

n20/D 1.451 (lit.)

p.e.

51 °C/19 mmHg (lit.)

solubilidade

water: insoluble

densidade

1.497 g/mL at 25 °C (lit.)

grupo funcional

bromo
ester

cadeia de caracteres SMILES

COC(=O)C(C)Br

InChI

1S/C4H7BrO2/c1-3(5)4(6)7-2/h3H,1-2H3

chave InChI

ACEONLNNWKIPTM-UHFFFAOYSA-N

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Categorias relacionadas

Aplicação

Methyl 2-bromopropionate was used as initiator during the synthesis of polymer brushes with single-walled carbon nanotubes as backbones. It was used as starting reagent for the synthesis of 2-18F-fluoropropionic acid, positron emission tomography imaging agent for prostate cancer.

Palavra indicadora

Danger

Frases de perigo

H226,H314,H335

Classificações de perigo

Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1B - STOT SE 3

Órgãos-alvo

Respiratory system

Código de classe de armazenamento

3 - Flammable liquids

Classe de risco de água (WGK)

WGK 3

Ponto de fulgor (°F)

125.6 °F - closed cup

Ponto de fulgor (°C)

52 °C - closed cup

Equipamento de proteção individual

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

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Certificados de análise (COA)

Lot/Batch Number
MKCQ1860
MKCM4075
MKCJ7662
MKCL1595
MKCH6296

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Gerard Lligadas et al.
Biomacromolecules, 18(10), 2981-3008 (2017-08-30)
The most fundamental aspects of single-electron transfer (SET) principles are presented. They are discussed according to different definitions used by expert practitioners and are applied to SET living radical polymerization (SET-LRP) according to the definition of the division of organic
Nagavarakishore Pillarsetty et al.
Journal of nuclear medicine : official publication, Society of Nuclear Medicine, 50(10), 1709-1714 (2009-09-18)
There is a high interest in developing an (18)F-labeled PET tracer that can aid in diagnosis and therapy monitoring of prostate cancer. In the current study, we have evaluated the potential of 2-(18)F-fluoropropionic acid ((18)F-FPA) as a PET tracer for
Shuhui Qin et al.
Journal of the American Chemical Society, 126(1), 170-176 (2004-01-08)
Polymer brushes with single-walled carbon nanotubes (SWNT) as backbones were synthesized by grafting n-butyl methacrylate (nBMA) from the ends and sidewalls of SWNT via atom transfer radical polymerization (ATRP). Carboxylic acid groups on SWNT were formed by nitric acid oxidation.
Yu Wang
Polymers, 11(8) (2019-07-31)
Atom transfer radical polymerization (ATRP) of methyl acrylate (MA) was carried out by continuous feeding of Cu(I) activators. Typically, the solvent, the monomer, the initiator, and the CuBr2/Me6TREN deactivator are placed in a Schlenk flask (Me6TREN: tris[2-(dimethylamino)ethyl]amine), while the CuBr/Me6TREN
Federico Di Sacco et al.
Nanomaterials (Basel, Switzerland), 9(3) (2019-03-22)
Novel, multipurpose terpolymers based on styrene (PS), tert-butyl methacrylate (tBMA) and glycidyl methacrylate (GMA), have been synthesized via Atom Transfer Radical Polymerization (ATRP). Post-synthetic modification with 1-pyrenemethylamine (AMP) allows non-covalent functionalization of carbon nanotubes, eventually yielding a conductive nanocomposite materials
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