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156876

Sigma-Aldrich

N-(2-Hydroxyethyl)aniline

98%

Sinônimo(s):

2-(Phenylamino)ethanol, 2-Anilinoethanol, N-Phenylethanolamine

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About This Item

Fórmula linear:
C6H5NHCH2CH2OH
Número CAS:
122-98-5
Peso molecular:
137.18
Beilstein:
774672
Número MDL:
MFCD00002832
Código UNSPSC:
12352100
ID de substância PubChem:
24849642
NACRES:
NA.22

densidade de vapor

>1 (vs air)

Nível de qualidade

200

pressão de vapor

<0.01 mmHg ( 20 °C)

Ensaio

98%

Formulário

liquid

índice de refração

n20/D 1.578 (lit.)

p.e.

278-282 °C/760 mmHg (lit.)

densidade

1.094 g/mL at 25 °C (lit.)

cadeia de caracteres SMILES

OCCNc1ccccc1

InChI

1S/C8H11NO/c10-7-6-9-8-4-2-1-3-5-8/h1-5,9-10H,6-7H2

chave InChI

MWGATWIBSKHFMR-UHFFFAOYSA-N

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Aplicação

N-(2-Hydroxyethyl)aniline was employed as substrate for human olfactory UDP-glucuronosyltransferase.

Palavra indicadora

Danger

Classificações de perigo

Acute Tox. 2 Dermal - Acute Tox. 3 Oral - Aquatic Chronic 2 - Eye Dam. 1 - STOT RE 2 - STOT SE 1

Órgãos-alvo

Blood, Blood,hematopoietic system

Código de classe de armazenamento

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

Classe de risco de água (WGK)

WGK 3

Ponto de fulgor (°F)

235.4 °F - closed cup

Ponto de fulgor (°C)

113 °C - closed cup

Equipamento de proteção individual

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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Certificados de análise (COA)

Lot/Batch Number
BCBL0248V
1433059V
1433059
1384616
1195456

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Mercedes Amat et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 17(28), 7724-7732 (2011-06-15)
Phenylglycinol-derived, unsaturated oxazolopiperidone lactams are extremely useful building blocks that undergo stereoselective conjugate addition reactions with organocuprates, enolates, and sulfur-stabilized anions, allowing the stereocontrolled introduction of substituents at the piperidine 4-position. The factors governing the exo- or endo-facial selectivity are
Alok K Awasthi et al.
The Journal of organic chemistry, 70(14), 5387-5397 (2005-07-02)
[reaction: see text] A practical, large-scale synthesis of a beta-amino ester 1 was developed. A chiral imine derived from (S)-phenylglycinol and 3-trimethylsilylpropanal was coupled with the Reformatsky reagent 3 with high diastereoselectivity (de > 98%) to give (SS)-4a as the
Katarina Babić et al.
Journal of chromatography. A, 1142(1), 84-92 (2006-10-19)
The performance of extractant impregnated resin (EIR) technology for chiral separation of amino-alcohols has been investigated. Phenylglycinol was selected as an archetype model enantiomer and azophenolic crown ether was used as a versatile enantioselective extractant. 1-Phenyloctane was selected as a
Mercedes Amat et al.
Chemical communications (Cambridge, England), (20)(20), 2935-2937 (2009-05-14)
The first total synthesis of (-)-16-episilicine has been completed from a phenylglycinol-derived bicyclic lactam, the key steps being stereoselective conjugate addition and alkylation reactions, and a ring-closing metathesis.
Marco Santarem et al.
The Journal of organic chemistry, 73(16), 6466-6469 (2008-07-22)
An efficient formal total synthesis of (+)-gephyrotoxin is described. The key step of our strategy relies on the diastereoselective reduction of a chiral pyrrolidine beta-enamino ester obtained by condensation of ( S)-phenylglycinol on a protected 8-hydroxy-3,6-dioxooctanoate.
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