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Merck

701122

Sigma-Aldrich

Iron(III) chloride

greener alternative

sublimed grade, ≥99.9% trace metals basis

Synonim(y):

Ferric chloride, Iron trichloride, Molysite

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About This Item

Wzór liniowy:
FeCl3
Numer CAS:
Masa cząsteczkowa:
162.20
Numer WE:
Numer MDL:
Kod UNSPSC:
12352302
Identyfikator substancji w PubChem:
NACRES:
NA.23

klasa czystości

sublimed grade

Poziom jakości

gęstość pary

5.61 (vs air)

ciśnienie pary

1 mmHg ( 194 °C)

Próba

≥99.9% trace metals basis

Postać

powder or crystals

przydatność reakcji

reagent type: catalyst
core: iron

charakterystyka ekologicznej alternatywy

Catalysis
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sustainability

Greener Alternative Product

metody

cell culture | mammalian: suitable

zanieczyszczenia

≤1000.0 ppm Trace Metal Analysis

mp

304 °C (lit.)

Zastosowanie

battery manufacturing

kategoria ekologicznej alternatywy

ciąg SMILES

Cl[Fe](Cl)Cl

InChI

1S/3ClH.Fe/h3*1H;/q;;;+3/p-3

Klucz InChI

RBTARNINKXHZNM-UHFFFAOYSA-K

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Opis ogólny

Iron(III) chloride is brownish to black crystalline solid that is highly soluble in water. As a moderately strong Lewis acid, FeCl3 can form complex compounds and adducts with Lewis bases, making it a useful catalyst in various chemical reactions.
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Zastosowanie

Iron(III) chloride can be used:
  • As a precursor to prepare Fe(III)-chlorophyll complex. Fe(III) enhances the performance of chlorophyll as a dye sensitizer in DSSCs by forming complex compounds with metal-ligand charge transfer properties, leading to increased efficiency and improved paramagnetic properties.
  • As a catalyst /modifying agent to prepare high performance porous carbon for lithium-ion battery anodes. The addition of FeCl3 enhances the graphitization of porous carbon without significantly affecting the layer spacing and also the specific surface area and pore volume of porous carbon.
  • As a co-catalyst to fabricate liquid catalyzed fuel cell (LCFC) for direct conversion from carbohydrates to electricity. It helps to improve the hydrolysis of carbohydrate and enhances the electron transfer from carbohydrates to anode.

The vapor-phase co-reductions with other metal halides by hydrogen results in finely divided intermetallics with applications as structural materials or compounds with useful thermoelectric, magnetic, and oxidation-resitance properties.
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Piktogramy

CorrosionExclamation mark

Hasło ostrzegawcze

Danger

Zwroty wskazujące rodzaj zagrożenia

Klasyfikacja zagrożeń

Acute Tox. 4 Oral - Eye Dam. 1 - Met. Corr. 1 - Skin Irrit. 2

Kod klasy składowania

8B - Non-combustible corrosive hazardous materials

Klasa zagrożenia wodnego (WGK)

WGK 1

Temperatura zapłonu (°F)

Not applicable

Temperatura zapłonu (°C)

Not applicable

Środki ochrony indywidualnej

dust mask type N95 (US), Eyeshields, Faceshields, Gloves


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Odwiedź Bibliotekę dokumentów

Klienci oglądali również te produkty

Optimum reaction conditions for the polymerization of pyrrole by iron (III) chloride in aqueous solution.
Armes SP.
Synthetic Metals, 20(3), 365-371 (1987)
Recent uses of iron (III) chloride in organic synthesis.
Diaz DD, et al.
Current Organic Chemistry, 10(4), 457-476 (2006)
Kailiang Wang et al.
The Journal of organic chemistry, 74(2), 935-938 (2008-12-05)
Easily available and nontoxic FeCl(3) catalyzes intramolecular oxidative coupling for the direct construction of the phenanthrene ring using meta-chloroperbenzoic acid as sole oxidant at room temperature in excellent yields. The mechanistic investigations show that FeCl(3)-catalyzed coupling proceeds through the heterolytic
Photoredox chemistry of iron (III) chloride and iron (III) perchlorate in aqueous media. A comparative study.
David F and David PG.
The Journal of Physical Chemistry, 80(6), 579-583 (1976)
Abdelwareth A O Sarhan et al.
Chemical Society reviews, 38(9), 2730-2744 (2009-08-20)
In this critical review, the use of iron(III) chloride in oxidative C-C couplings of arenes and related unsaturated compounds is presented and reviewed. The approach allows highly selective dimerisations of phenol derivatives, naphthols, and heterocyclic compounds. Sequential couplings give access

Produkty

Professor Randal Lee (University of Houston, USA) discusses design considerations for iron oxide magnetic nanospheres and nanocubes used for biosensing, including synthetic procedures, size, and shape. The effects of these variables are discussed for various volumetric-based and surface-based detection schemes.

Lithium-Ion Battery Performance: Dependence on Material Synthesis and Post‑Treatment Methods

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