Wszystkie zdjęcia(1)
Key Documents
520268
4,4′,4″-Tri-tert-Butyl-2,2′:6′,2″-terpyridine
95%
Synonim(y):
2,6-Bis[4-(tert-butyl)pyridin-2-yl)-4-(tert-butyl)pyridine
Zaloguj sięWyświetlanie cen organizacyjnych i kontraktowych
About This Item
Wzór empiryczny (zapis Hilla):
C27H35N3
Numer CAS:
Masa cząsteczkowa:
401.59
Numer MDL:
Kod UNSPSC:
12352100
Identyfikator substancji w PubChem:
NACRES:
NA.22
Polecane produkty
Próba
95%
zanieczyszczenia
oligomers of tert-butyl-terpyridine
mp
215-217 °C (lit.)
ciąg SMILES
CC(C)(C)c1ccnc(c1)-c2cc(cc(n2)-c3cc(ccn3)C(C)(C)C)C(C)(C)C
InChI
1S/C27H35N3/c1-25(2,3)18-10-12-28-21(14-18)23-16-20(27(7,8)9)17-24(30-23)22-15-19(11-13-29-22)26(4,5)6/h10-17H,1-9H3
Klucz InChI
QMABMHJGSFUTPF-UHFFFAOYSA-N
Zastosowanie
4,4′,4-Tri-tert-Butyl-2,2′:6′,2-terpyridine can be used as a ligand:
- In the synthesis of methylated alkanes and ketones via Ni-catalyzed methylation of unactivated alkyl halides and acid chlorides.
- In Ni-catalyzed reductive dimerization reaction.
- In allylic defluorinative reductive cross-coupling reaction in the presence of Ni as a catalyst.
This page may contain text that has been machine translated.
Kod klasy składowania
11 - Combustible Solids
Klasa zagrożenia wodnego (WGK)
WGK 3
Temperatura zapłonu (°F)
Not applicable
Temperatura zapłonu (°C)
Not applicable
Wybierz jedną z najnowszych wersji:
Masz już ten produkt?
Dokumenty związane z niedawno zakupionymi produktami zostały zamieszczone w Bibliotece dokumentów.
Klienci oglądali również te produkty
![2,6-Bis[(4R)-(+)-isopropyl-2-oxazolin-2-yl]pyridine 99%](/deepweb/assets/sigmaaldrich/product/structures/349/609/8673c46e-368a-47a6-a9bd-52bbe13d490a/640/8673c46e-368a-47a6-a9bd-52bbe13d490a.png)
Zhuye Liang et al.
Organic letters, 16(21), 5620-5623 (2014-10-22)
Methylation of unactivated alkyl halides and acid chlorides under Ni-catalyzed reductive coupling conditions led to efficient formation of methylated alkanes and ketones using methyl p-methyl tosylate as the methylation reagent. Moderate to excellent coupling yields as well as excellent functional
Xiao-Yu Lu et al.
Organic & biomolecular chemistry, 18(19), 3674-3678 (2020-05-08)
A nickel-catalyzed defluorinative reductive cross-coupling of trifluoromethyl alkenes with epoxides has been developed. Various substituted trifluoromethyl alkenes and epoxides were found to be suitable reaction substrates. This reaction enabled C(sp3)-C(sp3) bond construction through allylic defluorinative cross-coupling of trifluoromethyl alkenes under
Michael R Prinsell et al.
Chemical communications (Cambridge, England), 46(31), 5743-5745 (2010-06-29)
The first general method for the reductive dimerization of alkyl halides, alkyl mesylates, alkyl trifluoroacetates, and allylic acetates is reported which proceeds with low catalyst loading (0.5 to 5 mol%), generally high yields (80% ave yield), and good functional-group tolerance.
Cheng-Pan Zhang et al.
Journal of the American Chemical Society, 135(22), 8141-8144 (2013-05-23)
Mechanistic proposals for nickel-catalyzed coupling reactions often invoke five-coordinate alkyl- or aryl-bound Ni(II) and/or high-valent nickel(III) species, but because of their reactive nature, they have been difficult to study and fingerprint. In this work, we invoked the stabilizing properties of
Gavin D Jones et al.
Journal of the American Chemical Society, 128(40), 13175-13183 (2006-10-05)
The ability of the terpyridine ligand to stabilize alkyl complexes of nickel has been central in obtaining a fundamental understanding of the key processes involved in alkyl-alkyl cross-coupling reactions. Here, mechanistic studies using isotopically labeled (TMEDA)NiMe(2) (TMEDA = N,N,N',N'-tetramethylethylenediamine) have
Nasz zespół naukowców ma doświadczenie we wszystkich obszarach badań, w tym w naukach przyrodniczych, materiałoznawstwie, syntezie chemicznej, chromatografii, analityce i wielu innych dziedzinach.
Skontaktuj się z zespołem ds. pomocy technicznej