346276

Tetrakis(acetonitrile)copper(I) hexafluorophosphate

97%

• Synonim(y): Copper(I) tetrakis(acetonitrile) hexafluorophosphate, Cuprous tetrakis(acetonitrile) hexafluorophosphate
• Wzór liniowy: [(CH₃CN)₄Cu]PF₆
• Numer CAS: 64443-05-6
• Masa cząsteczkowa: 372.72
• Numer MDL: MFCD00064810
• Kod UNSPSC: 12161600
• Identyfikator substancji w PubChem: 24861387
• NACRES: NA.22

Właściwości

• Poziom jakości: 100
• Próba: 97%
• Postać: solid
• przydatność reakcji: core: copper; reagent type: catalyst
• mp: 160 °C (dec.) (lit.)
• ciąg SMILES: [Cu+].CC#N.CC#N.CC#N.CC#N.F[P-](F)(F)(F)(F)F
• InChI: 1S/4C2H3N.Cu.F6P/c4*1-2-3;;1-7(2,3,4,5)6/h4*1H3;;/q;;;;+1;-1
• Klucz InChI: GNQXUMGHBSAQBV-UHFFFAOYSA-N

Opis

Zastosowanie

Tetrakis(acetonitrile)copper(I) hexafluorophosphate can be employed as a catalyst for the synthesis of triazolo[1,2-a]indazole-1,3,8-trione and 2H-indazolo[2,1-b]phthalazine-trione derivatives by the reaction of aryl aldehydes, dimedone and urazole or phthalhydrazide, respectively.
It can also be used as a copper precursor:

• For the formation of Cu₂S/CdS nanorod junctions by cationic exchange process.
• To synthesize monometallic copper macrocyclic biquinazoline ligand [Cu(Mabiq)].
• To prepare the cuprous complex [Cu(2-iQBO)(POP)]PF₆]; where 2-iQBO=2-(1′-isoquinolyl)benzoxazole and POP=bis[2-(diphenylphosphino)phenyl]ether, which can form luminescent pseudo-polymorphs.
• For the synthesis of [Cu(NHC)₂]PF₆ complexes [(NHC = N-heterocyclic carbene] which can be further used in the hydrosilylation of carbonyl compounds.

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Informacja o środkach bezpieczeństwa

• Kod klasy składowania: 11 - Combustible Solids
• Klasa zagrożenia wodnego (WGK): WGK 3
• Temperatura zapłonu (°F): Not applicable
• Temperatura zapłonu (°C): Not applicable
• Środki ochrony indywidualnej: Eyeshields, Gloves, type N95 (US)