938688

ImPy-Dipp-IMes

• 別名: 5-(2,6-diisopropylphenyl)-2-mesitylimidazo[1,5-a]pyridin-2-ium chloride
• 実験式（ヒル表記法）: C₂₈H₃₃ClN₂
• CAS番号: 2983007-39-0
• 分子量: 433.03
• UNSPSCコード: 12352100
• NACRES: NA.21

特性

• フォーム: powder
• 品質水準: 100
• 反応適合性: reaction type: Cross Couplings
• 環境により配慮した代替製品の特徴: Catalysis; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• 色: white
• 環境により配慮した代替製品カテゴリ: Aligned
• SMILES記法: CC1=CC(C)=CC(C)=C1[N+]2=CN3C(C4=C(C(C)C)C=CC=C4C(C)C)=CC=CC3=C2.[Cl-]
• InChI: 1S/C28H33N2.ClH/c1-18(2)24-11-9-12-25(19(3)4)27(24)26-13-8-10-23-16-29(17-30(23)26)28-21(6)14-20(5)15-22(28)7;/h8-19H,1-7H3;1H/q+1;/p-1
• InChI Key: BQLNHZQDABCIAO-UHFFFAOYSA-M

詳細

詳細

ImPy-Dipp-IMes is an NHC precursor developed in the Szostak group. The ligand is useful in a range of catalytic transformations, and is particularly well suited to the following: Suzuki-Miyaura cross-coupling of aryl mesylates and tosylates, Suzuki–Miyaura cross-coupling of nitroarenes (Ar–NO₂), Buchwald-Hartwig amination of alkyl sulfoxides.

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Green Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

アプリケーション

Suzuki-Miyaura cross-coupling of aryl mesylates and tosylates Suzuki–Miyaura cross-coupling of nitroarenes (Ar–NO₂) or aryl sulfamates Buchwald-Hartwig amination of alkyl sulfoxides or aryl sulfamates.

特徴および利点

ImPy-Dipp-Imes is an asymmetric NHC ligand precursor. It forms air-and moisture stable complexes with transition metals and is particularly effective in palladium catalyzed cross-coupling reactions.

安全性情報

• 保管分類コード: 11 - Combustible Solids
• WGK: WGK 3
• 引火点(°F): Not applicable
• 引火点(℃): Not applicable