901166

cis-[2,2′-Bis(diphenylphosphino)-1,1′-binaphthyl](2-methylphenyl)nickel(II) chloride

• 別名: cis-((S)-BINAP)Ni(o-tolyl)Cl
• 実験式（ヒル表記法）: C₅₁H₃₉ClNiP₂
• CAS番号: 1594113-05-9
• 分子量: 807.95
• UNSPSCコード: 12161600
• NACRES: NA.22

特性

• 形状: powder or solid
• 品質水準: 100
• 反応適合性: core: nickel; reaction type: Cross Couplings; reagent type: catalyst
• mp: >300 °C
• SMILES記法: Cl[Ni]1(P(C2=C([H])C([H])=C([H])C([H])=C2[H])(C3=C([H])C([H])=C([H])C([H])=C3[H])C(C([H])=C4[H])=[C@@]([C@@]5=C(P1(C6=C([H])C([H])=C([H])C([H])=C6[H])C7=C([H])C([H])=C([H])C([H])=C7[H])C([H])=C([H])C8=C5C([H])=C([H])C([H])=C8[H])C9=C4C([H])=C([H])C([H])=C

詳細

アプリケーション

The following Ni-complex is an air-stable precatalyst for various Ni-catalyzed reactions which normally require Ni(cod)₂, however, this precatalyst will not require any glovebox or schlenk techniques that must be followed with Ni(cod)₂. Rates are enhanced and selectivity is maintained when compared to the same reaction with Ni(cod)₂.

その他情報

• Technology Spotlight: Jamison Nickel (II) Precatalysts
• A Broadly Applicable Strategy for Entry into Homogeneous Nickel(0) Catalysts from Air-Stable Nickel(II) Complexes

法的情報

Patent application PCT/US2014/064565. Sold under license from the Massachusetts Institute of Technology.

安全性情報

• 保管分類コード: 4.1B - Flammable solid hazardous materials
• WGK: WGK 3
• 引火点(°F): Not applicable
• 引火点(℃): Not applicable