794279

Chloro(2-methylphenyl)bis(triphenylphosphine)nickel(II)

• 別名: Buchwald Nickel Cross-Coupling Catalyst Precursor, [Bis(triphenylphosphine)](o-tolyl)chloronickel
• 実験式（ヒル表記法）: C₄₃H₃₇ClNiP₂
• CAS番号: 27057-09-6
• 分子量: 709.85
• UNSPSCコード: 12161600
• PubChem Substance ID: 329768436
• NACRES: NA.22

特性

• 形状: solid
• 品質水準: 100
• 反応適合性: core: nickel; reagent type: catalyst
• mp: 195-200 °C
• 保管温度: 2-8°C
• SMILES記法: Cl[Ni]C1=CC=CC=C1C.P(C2=CC=CC=C2)(C3=CC=CC=C3)C4=CC=CC=C4.P(C5=CC=CC=C5)(C6=CC=CC=C6)C7=CC=CC=C7
• InChI: 1S/2C18H15P.C7H7.ClH.Ni/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-7-5-3-2-4-6-7;;/h2*1-15H;2-5H,1H3;1H;/q;;;;+1/p-1
• InChI Key: QVGJKVLYWZGANE-UHFFFAOYSA-M

詳細

アプリケーション

Product is a precursor to the synthesis of an air-stable Ni-precatalyst developed by Buchwald and coworkers.

その他情報

Development of an Air-Stable Nickel Precatalyst for the Amination of Aryl Chlorides, Sulfamates, Mesylates, and Triflates

安全性情報

• ピクトグラム: GHS08,GHS07
• シグナルワード: Danger
• 危険有害性情報: H317,H350
• 注意書き: P201 - P280 - P302 + P352 - P308 + P313
• 危険有害性の分類: Carc. 1B - Skin Sens. 1
• 保管分類コード: 6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
• WGK: WGK 3
• 引火点(°F): Not applicable
• 引火点(℃): Not applicable