802948

(dppf)Ni(o-tolyl)Cl

• 別名: Buchwald Ni Catalyst
• 実験式（ヒル表記法）: C₄₁H₃₅ClFeNiP₂
• CAS番号: 1501945-23-8
• 分子量: 739.66
• MDL番号: MFCD28411349
• UNSPSCコード: 12161600
• PubChem Substance ID: 329768766
• NACRES: NA.22

特性

• アッセイ: 95%
• 品質水準: 100
• 形状: powder
• 反応適合性: core: nickel; reaction type: Cross Couplings; reagent type: catalyst
• mp: 173 °C
• 保管温度: 2-8°C
• SMILES記法: CC1=CC=CC=C1[Ni]Cl.[C]2(P(C3=CC=CC=C3)C4=CC=CC=C4)[C][C][C][C]2.[C]5(P(C6=CC=CC=C6)C7=CC=CC=C7)[C][C][C][C]5.[Fe]
• InChI: 1S/2C17H14P.C7H7.ClH.Fe.Ni/c2*1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;1-7-5-3-2-4-6-7;;;/h2*1-14H;2-5H,1H3;1H;;/q;;;;;+1/p-1
• InChI Key: LGLPATFHWYLMCO-UHFFFAOYSA-M

詳細

詳細

(dppf)Ni(o-tolyl)Cl is an air stable reagent. Its crystal structure has been investigated by X-ray studies. (dppf)Ni(o-tolyl)Cl can be prepared from (Ph₃P)₂Ni(o-tolyl)Cl. It is widely employed as a precatalyst for various C-N bond formation reactions. Efficacy of (dppf)Ni(o-tolyl)Cl as a precatalyst for the amination of 4-n-butylchlorobenzene with morpholine under various optimized reaction conditions has been investigated.

安全性情報

• ピクトグラム: GHS08,GHS09
• シグナルワード: Danger
• 危険有害性情報: H317,H334,H341,H350,H360,H372,H410
• 注意書き: P201 - P273 - P280 - P302 + P352 - P308 + P313
• 危険有害性の分類: Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1A - Muta. 2 - Repr. 1B - Resp. Sens. 1 - Skin Sens. 1 - STOT RE 1 Inhalation
• 保管分類コード: 6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
• WGK: WGK 3
• 引火点(°F): Not applicable
• 引火点(℃): Not applicable