901165

trans-Bis(tricyclohexylphosphine)(2-methylphenyl)nickel(II) chloride

≥95%

• 別名: trans-(PCy₃)₂Ni(o-tolyl)Cl
• 実験式（ヒル表記法）: C₄₃H₇₃ClNiP₂
• CAS番号: 123839-28-1
• 分子量: 746.13
• UNSPSCコード: 12352200

特性

• アッセイ: ≥95%
• 形状: powder or solid
• 反応適合性: core: nickel; reaction type: Cross Couplings; reagent type: catalyst
• mp: >300 °C
• SMILES記法: Cl[Ni](C1=C(C)C=CC=C1)(P(C2CCCCC2)(C3CCCCC3)C4CCCCC4)P(C5CCCCC5)(C6CCCCC6)C7CCCCC7

詳細

アプリケーション

The following Ni-complex is an air-stable precatalyst for various Ni-catalyzed reactions which normally require Ni(cod)₂, however, this precatalyst will not require any glovebox or schlenk techniques that must be followed with Ni(cod)₂. Rates are enhanced and selectivity is maintained when compared to the same reaction with Ni(cod)₂.

その他情報

• Technology Spotlight: Jamison Nickel (II) Precatalysts
• A Broadly Applicable Strategy for Entry into Homogeneous Nickel(0) Catalysts from Air-Stable Nickel(II) Complexes

法的情報

Patent application PCT/US2014/064565. Sold under license from the Massachusetts Institute of Technology.

安全性情報

• 保管分類コード: 4.1B - Flammable solid hazardous materials
• WGK: WGK 3
• 引火点(°F): Not applicable
• 引火点(℃): Not applicable