87189

1-テトラデセン

≥97.0% (GC)

• 別名: 1-Butadecene, n-Tetradec-1-ene, alpha-Tetradecene
• 化学式: CH₃(CH₂)₁₁CH=CH₂
• CAS番号: 1120-36-1
• 分子量: 196.37
• Beilstein: 1701156
• EC Number: 214-306-9
• MDL番号: MFCD00008981
• UNSPSCコード: 12352100
• PubChem Substance ID: 57653175
• NACRES: NA.22

特性

• 蒸気密度: 6.8 (vs air)
• アッセイ: ≥97.0% (GC)
• フォーム: liquid
• 自己発火温度: 455 °F
• 屈折率: n20/D 1.436 (lit.); n20/D 1.436
• bp: 251 °C (lit.)
• mp: −13-−11 °C (lit.)
• 密度: 0.775 g/mL at 25 °C (lit.)
• 官能基: allyl
• SMILES記法: CCCCCCCCCCCCC=C
• InChI: 1S/C14H28/c1-3-5-7-9-11-13-14-12-10-8-6-4-2/h3H,1,4-14H2,2H3
• InChI Key: HFDVRLIODXPAHB-UHFFFAOYSA-N

詳細

アプリケーション

1-Tetradecene can be used as a reactant to synthesize:

• 2-Tetradecanone via PdCl₂/CrO₃ catalyzed oxidation reaction.
• (E)-ethyl pentadec-2-enoate, which is used as a key intermediate in the diastereoselective synthesis of (+)-nephrosterinic acid and (+)-protolichesterinic acid via Johnson-Claisen rearrangement.

It can also be used as a monomer unit to synthesize high molecular weight polymer [poly(1- tetradecene)] by titanium complex catalyzed polymerization reaction.

安全性情報

• ピクトグラム: GHS08
• シグナルワード: Danger
• 危険有害性情報: H304
• 注意書き: P301 + P310 - P331 - P405 - P501
• 危険有害性の分類: Asp. Tox. 1
• 補足的ハザード: EUH066
• 保管分類コード: 10 - Combustible liquids
• WGK: WGK 3
• 引火点(°F): 230.0 °F
• 引火点(℃): 110 °C
• 個人用保護具 (PPE): Eyeshields, Gloves, type ABEK (EN14387) respirator filter