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923222

Sigma-Aldrich

Poly(9,9-dioctylfluorenyl-2,7-diyl) end capped with dimethylphenyl

greener alternative

Mw 50,000-150,000 by GPC

Sinonimo/i:

PFO-DMP

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About This Item

Formula condensata:
C16H18(C29H40)n
Numero CAS:
Codice UNSPSC:
12352103
NACRES:
NA.23

Descrizione

PL: 421 nm in THF

Livello qualitativo

PM

Mw 50,000-150,000 by GPC

Caratteristiche più verdi

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

Banda proibita

2.5 eV

Solubilità

THF: soluble
chlorobenzene: soluble
chloroform: soluble
dichlorobenzene: soluble

λmax

368 nm in THF

Energia dell’orbitale

HOMO -5.3 eV 
LUMO -2.8 eV 

Categoria alternativa più verde

Descrizione generale

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product belongs to Enabling category of greener alternatives thus aligns with "Design for energy efficency". Hole transport organic materials allow perfect energy level alignment with the absorber layer and therefore efficient charge collection, are prone to degradation in ambient conditions.Click here for more information.

Applicazioni

Highly emissive poly(9,9-dioctylfluorenyl-2, 7-diyl) end capped with dimethylphenyl (PFO-DMP) is a conjugated polymer with white light emision, remarkable thermal stability and high photo- and electroluminescence efficiency. PFO-DMP was successfully demonstrated in textile digital printing for organic light emission devices (OLEDs) , as well as in high voltage composite separator in Lithium batteries at high rates and low temperatures.
PFO-DMPP can be used as an active material in the fabrication of LEDs. The modification with dimethylphenyl end-capping groups can enhance the charge injection and transport characteristics, leading to improved device efficiency and stability. It can be used in applications in OPV devices, particularly as a donor material. The end-capping with dimethylphenyl groups can modify the energy levels and molecular packing, impacting the optical and electrical properties. PFO-DMPP can be utilized as an active layer in organic thin-film transistors (OTFTs) due to its improved charge transport characteristics. The end-capping groups help to enhance the carrier mobility and improve the performance of the transistors. This modification can influence the power conversion efficiency of the OPV cells.

Codice della classe di stoccaggio

11 - Combustible Solids

Classe di pericolosità dell'acqua (WGK)

WGK 3

Punto d’infiammabilità (°F)

Not applicable

Punto d’infiammabilità (°C)

Not applicable


Certificati d'analisi (COA)

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Overcharge Protection for 4 V Lithium Batteries at High Rates and Low Temperatures.
Chen G, et al.
Journal of the Electrochemical Society, 157, A735-A740 (2010)
Efficient white light emission in conjugated polymer homojunctions.
Ho G K, et al.
Applied Physics Letters, 85, 4576-4578 (2004)
Characterization of digital textile printing and polymer blend (PFO-DMP:P3HT) for application in manufacture of organic diodes emitting white light - WOLEDS.
Da Silva M A T, et al.
Optical Materials, 62, 119-131 (2016)

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