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Sigma-Aldrich

Platinum(II) acetylacetonate

97%

Sinonimo/i:

2,4-Pentanedione platinum(II) derivative, Pt(acac)2

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About This Item

Formula condensata:
Pt(C5H7O2)2
Numero CAS:
15170-57-7
Peso molecolare:
393.29
Beilstein:
4136189
Numero CE:
239-223-5
Numero MDL:
MFCD00000028
Codice UNSPSC:
12352103
ID PubChem:
24857069
NACRES:
NA.23

Saggio

97%

Forma fisica

solid

Impiego in reazioni chimiche

core: platinum
reagent type: catalyst

Punto di fusione

249-252 °C (lit.)

Stringa SMILE

CC(=O)\C=C(\C)O[Pt]O\C(C)=C/C(C)=O

InChI

1S/2C5H8O2.Pt/c2*1-4(6)3-5(2)7;/h2*3,6H,1-2H3;/q;;+2/p-2/b2*4-3-;
KLFRPGNCEJNEKU-FDGPNNRMSA-L

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Categorie correlate

Descrizione generale

Platinum(II)acetylacetonate is widely used as a Ptsource and precursor in the preparation of nanocatalysts and films. It is alsoused as a catalyst in N-allylation reactions.

Applicazioni

Platinum(II)acetylacetonate can be used as an efficient catalyst:
  • In the preparation of N-allylanilines by the direct use of allylic alcohols. Anilines with electron-donating groups give good yields.
  • For selective N-allylation of 2,3-disubstituted indoles in water.
Pt-loaded ZnO thick films can be prepared by flame spray pyrolysis method using zinc naphthenate and platinum(II) acetylacetonate as precursors. These sensing films can be used for acetylene detection and show good selectivity towards carbon monoxide, hydrogen, and methane.

It can be used as a starting material in the preparation of platinum-lead nanoparticles supported on carbon. The PtPb/C catalyst exhibits enhanced electrochemical activity towards methanol and formic acid oxidation.

Pittogrammi

Health hazardExclamation mark
GHS08,GHS07

Avvertenze

Warning

Classi di pericolo

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Repr. 2 - Skin Irrit. 2 - STOT SE 3

Organi bersaglio

Respiratory system

Codice della classe di stoccaggio

11 - Combustible Solids

Classe di pericolosità dell'acqua (WGK)

WGK 3

Punto d’infiammabilità (°F)

Not applicable

Punto d’infiammabilità (°C)

Not applicable

Dispositivi di protezione individuale

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges

Certificati d'analisi (COA)

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Chemistry Letters (Jpn), 33, 658-659 (2004)
Chemistry of Materials, 18, 6414-6414 (2006)
Xiaochen Shen et al.
Nature communications, 9(1), 4485-4485 (2018-10-28)
Understanding the growth pathway of faceted alloy nanoparticles at the atomic level is crucial to morphology control and property tuning. Yet, it remains a challenge due to complexity of the growth process and technical limits of modern characterization tools. We
Jin Wang et al.
Nanoscale research letters, 14(1), 11-11 (2019-01-10)
Electrochemical sensors have the high sensitivity, fast response, and simple operation for applications in biological, medical, and chemical detection, but limited by the poor stability and high cost of the electrode materials. In this work, we used PtNi lagged-like nanowire
Chemistry of Materials, 16, 2363-2368 (2004)
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