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208043

Sigma-Aldrich

Sodium sulfide nonahydrate

ACS reagent, ≥98.0%

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About This Item

Fórmula linear:
Na2S·9H2O
Número CAS:
1313-84-4
Peso molecular:
240.18
Número CE:
215-211-5
Número MDL:
MFCD00149184
Código UNSPSC:
12352302
ID de substância PubChem:
329752036
NACRES:
NA.21

grau

ACS reagent

Ensaio

≥98.0%

forma

crystals or chunks

adequação da reação

reagent type: catalyst
core: sodium

cor

colorless to slightly yellow

traços de ânion

SO32- and S2O32-: ≤0.1%

traços de cátion

Fe:, passes test
NH4+: ≤0.005%

temperatura de armazenamento

2-8°C

cadeia de caracteres SMILES

O.O.O.O.O.O.O.O.O.[Na]S[Na]

InChI

1S/2Na.9H2O.S/h;;9*1H2;

chave InChI

UIINQVYGFKNSPA-UHFFFAOYSA-N

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Descrição geral

Sodium sulfide nonahydrate participates in the conversion of nitroxides to amines, via reduction.

Aplicação

Sodium sulfide nonahydrate has been used as a source of H2S, to study the effect of H2S on amyloid fibrils associated with neurodegenerative diseases. It has been used in the preparation of sulfide standards for the quantitative analysis of sulfides in raw wastewater (sewage) samples.
It serves as a catalyst during synthesis of thioamides.
Sodium sulfide nonahydrate has been used as a standard for the quantification of volatile sulfur compounds in cheese samples by gas chromatography. It reacts with 4-(2′-hydroxyaryl)-2-(N,N-dialkylamino)-1,3-dithiolium perchlorates in ethanol at room temperature and boiling ethanol to form 1,3-dithiole-2-thiones and 2′-hydroxyacetophenones, respectively. Sodium sulfide nonahydrate may be used as a reducing agent for the conversion of vic-dibromides to the corresponding olefins via reductive debromination.

Palavra indicadora

Danger

Frases de perigo

H302,H311,H314,H410

Classificações de perigo

Acute Tox. 3 Dermal - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Corr. 1B

Código de classe de armazenamento

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

Classe de risco de água (WGK)

WGK 3

Ponto de fulgor (°F)

Not applicable

Ponto de fulgor (°C)

Not applicable

Certificados de análise (COA)

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Preservation and simultaneous analysis of relevant soluble sulfur species in sewage samples
Keller-Lehmann B, et al.
Proceedings of the 2nd International Conference on Intelligent Technologies and Engineering Systems (ICITES2013). Springer International Publishing, 2014., 26 (2006)
Daniel L Priebbenow et al.
Chemical Society reviews, 42(19), 7870-7880 (2013-06-25)
The Willgerodt-Kindler reaction has, in recent years, received limited attention and application in synthetic organic chemistry. With the advent of new technology such as microwave-assisted heating, several new, high-yielding, practical, and more environmentally friendly reaction protocols have been developed. This
Reduction of nitroxides to amines by sodium sulfide.
Kornblum N and Pinnick HW.
The Journal of Organic Chemistry, 37(12), 2050-2051 (1972)
Manuel F Rosario-Alomar et al.
The journal of physical chemistry. B, 119(4), 1265-1274 (2014-12-30)
Amyloid fibrils are large aggregates of misfolded proteins, which are often associated with various neurodegenerative diseases such as Alzheimer's, Parkinson's, Huntington's, and vascular dementia. The amount of hydrogen sulfide (H2S) is known to be significantly reduced in the brain tissue
Reaction of 4-(2'-Hydroxyaryl)-1, 3-dithiolium Salts with Sodium Sulfide. A Selective Synthesis of 2'-Hydroxyacetophenones.
Birsa ML.
Synthetic Communications, 33(17), 3071-3076 (2003)
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