00375

4-Acetamido-2,2,6,6-tetramethylpiperidine 1-oxyl

purum, ≥98.0% (HPLC)

• Fórmula empírica (Notação de Hill): C₁₁H₂₁N₂O₂
• Número CAS: 14691-89-5
• Peso molecular: 213.30
• Beilstein: 3546225
• Número CE: 423-840-3
• Número MDL: MFCD00043593
• Código UNSPSC: 12352005
• ID de substância PubChem: 329747053
• NACRES: NA.22

Propriedades

• grau: purum
• Nível de qualidade: 200
• Ensaio: ≥98.0% (HPLC)
• pontuação do produto alternativo mais ecológico: old score: 9; new score: 8; Find out more about DOZN™ Scoring
• características do produto alternativo mais ecológico: Waste Prevention; Safer Solvents and Auxiliaries; Inherently Safer Chemistry for Accident Prevention; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• pf: 143-145 °C (lit.); 143-146 °C
• grupo funcional: amide
• categoria alternativa mais ecológica: , Re-engineered
• temperatura de armazenamento: 2-8°C
• cadeia de caracteres SMILES: CC(=O)NC1CC(C)(C)N([O])C(C)(C)C1
• InChI: 1S/C11H21N2O2/c1-8(14)12-9-6-10(2,3)13(15)11(4,5)7-9/h9H,6-7H2,1-5H3,(H,12,14)
• chave InChI: UXBLSWOMIHTQPH-UHFFFAOYSA-N

Descrição

Descrição geral

4-Acetamido-2,2,6,6-tetramethylpiperidine 1-oxyl undergoes one-electron oxidation and reduction reactions. Reaction products were analyzed by ¹H, ¹³C and ¹⁵N NMR spectral data.

We are committed to bringing you Greener Alternative Products, which adhere to one of the four categories of Greener Alternatives . This product belongs to category of Re-engineered products, showing key improvements in Green Chemistry Principles “Waste Prevention”, “Safer Solvents and Auxiliaries” and “Inherently Safer Chemistry for Accident Prevention”. Click here to view its DOZN scorecard.

Aplicação

4-Acetamido-2,2,6,6-tetramethylpiperidine 1-oxyl radical may be employed in the catalytic system used for the regioselective oxidation of curdlan. It may be employed as model nitroxyl radical to study its reaction with thiophosgene. Reaction afforded 2,2,6,6-tetramethylpiperidine and 2,2,6,6-tetramethyl-1-hydroxypiperidine as major products.

Outras notas

New oxidant for the mild oxidation of alcohols to carbonyls

Informações de segurança

• Pictogramas: GHS07
• Palavra indicadora: Warning
• Frases de perigo: H302
• Declarações de precaução: P264 - P270 - P301 + P312 - P501
• Classificações de perigo: Acute Tox. 4 Oral
• Código de classe de armazenamento: 11 - Combustible Solids
• Classe de risco de água (WGK): WGK 1
• Ponto de fulgor (°F): Not applicable
• Ponto de fulgor (°C): Not applicable
• Equipamento de proteção individual: dust mask type N95 (US), Eyeshields, Gloves