ALD00378

Wasa-Yu MPAA Ligand

• Sinônimo(s): (S)-3-(2,6-Difluorophenyl)-2-((((4-(trichloromethyl)heptan-4- yl)oxy)carbonyl)amino)propanoic acid
• Fórmula empírica (Notação de Hill): C₁₈H₂₂Cl₃F₂NO₄
• Número CAS: 1346641-35-7
• Peso molecular: 460.73
• Código UNSPSC: 12352101
• ID de substância PubChem: 329772660
• NACRES: NA.22

Propriedades

• forma: solid
• adequação da reação: reaction type: C-H Activation; reagent type: catalyst; reagent type: ligand; reaction type: Peptide Synthesis
• pb: 521.1 °C±50.0 °C
• densidade: 1.365 g/cm³±0.06 g/cm³
• grupo funcional: amine; carboxylic acid
• temperatura de armazenamento: 2-8°C
• cadeia de caracteres SMILES: O=C(O)[C@@H](NC(OC(CCC)(CCC)C(Cl)(Cl)Cl)=O)CC1=C(F)C=CC=C1F
• InChI: 1S/C18H22Cl3F2NO4/c1-3-8-17(9-4-2,18(19,20)21)28-16(27)24-14(15(25)26)10-11-12(22)6-5-7-13(11)23/h5-7,14H,3-4,8-10H2,1-2H3,(H,24,27)(H,25,26)/t14-/m0/s1
• chave InChI: MYNBDMWXOQDYED-AWEZNQCLSA-N

Descrição

Aplicação

The Wasa-Yu MPAA Ligand has been reported by Yu and coworkers to promote the enantioselective C-H activation of cyclopropanes. This transformation is carried out through the coupling of organoboron reagents using palladium-mediated catalysis.

Outras notas

Pd(II)-Catalyzed Enantioselective C–H Activation of Cyclopropanes

Informações de segurança

• Código de classe de armazenamento: 11 - Combustible Solids
• Classe de risco de água (WGK): WGK 3
• Ponto de fulgor (°F): Not applicable
• Ponto de fulgor (°C): Not applicable