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743003

Sigma-Aldrich

2-Butanone peroxide

technical

Sinônimo(s):

Ethyl methyl ketone peroxide, Methyl ethyl ketone peroxide

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About This Item

Fórmula linear:
C2H5C(OOH)(CH3)OOC(OOH)(CH3)C2H5
Número CAS:
1338-23-4
Peso molecular:
210.22
Beilstein:
1759757
Número MDL:
MFCD00042641
Código UNSPSC:
12352120
ID de substância PubChem:
329765606
NACRES:
NA.22
Formulário:
liquid

grau

technical

Formulário

liquid

contém

2,2,4-trimethyl-1,3-pentanediol-diisobutyrate as stabilizer

adequação da reação

reagent type: oxidant

índice de refração

n20/D 1.432

densidade

1.053 g/mL at 20 °C (lit.)

grupo funcional

hydroperoxide
peroxide

temperatura de armazenamento

2-8°C

cadeia de caracteres SMILES

CCC(C)(OO)OOC(C)(CC)OO

InChI

1S/C8H18O6/c1-5-7(3,11-9)13-14-8(4,6-2)12-10/h9-10H,5-6H2,1-4H3

chave InChI

WFUGQJXVXHBTEM-UHFFFAOYSA-N

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Aplicação

Reactant for:
  • Studies of the adiabatic runaway reaction of Me Et Ketone peroxide
  • Quantitation of metal ions in archaeological glass via abrasive stripping square-wave voltammetry
  • Imaging of hydrogen peroxide and hydrogen peroxide-scavenging substances by photon emission
  • Synthesis of oligonucleotides via phosphoramidite method
  • Oxidation of nucleoside phosphites into phosphates
  • Comparing the relative effectiveness of human plasma glutathione peroxidase as a catalyst for reduction of hydroperoxidases

Analyte for direct electrochemical catalystis of immobilized Hb in an ethanol-water mixture

Palavra indicadora

Danger

Frases de perigo

H226,H242,H302,H314

Classificações de perigo

Acute Tox. 4 Oral - Flam. Liq. 3 - Org. Perox. D - Skin Corr. 1B

Código de classe de armazenamento

5.2 - Organic peroxides and self-reacting hazardous materials

Classe de risco de água (WGK)

WGK 1

Ponto de fulgor (°F)

132.8 °F - closed cup

Ponto de fulgor (°C)

56 °C - closed cup

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Certificados de análise (COA)

Lot/Batch Number
BCCF7634
BCCB0718
BCBV4363
BCBV2664
BCBG4416V

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2-Butanona Pharmaceutical Secondary Standard; Certified Reference Material

Supelco

PHR1207

2-Butanona

F T Fraunfelder et al.
American journal of ophthalmology, 110(6), 635-640 (1990-12-15)
Methyl ethyl ketone peroxide is a commonly used catalyst in various industries. We studied 19 eyes with a single exposure to methyl ethyl ketone peroxide that developed clinical patterns of mild injury, moderate injury, severe injury, or delayed keratitis. Delayed
M Ando et al.
Toxicology and applied pharmacology, 81(3 Pt 1), 517-524 (1985-12-01)
Some new aspects of damage to cytochrome P-450 peroxidase activities by a toxic peroxide were investigated. Methyl ethyl ketone peroxide (MEKP) damage to cytochrome P-450 and inhibition of cytochrome P-450-mediated peroxidase activities were studied. In vivo, hepatic microsomal NADH- and
M Ando et al.
Chemico-biological interactions, 55(3), 317-326 (1985-11-01)
The effect of dietary vitamin E on in vivo and in vitro damage by methyl ethyl ketone peroxide (MEKP) to cytochrome P-450 and its associated enzymatic activity was studied. In vivo, MEKP damaged microsomal cytochrome P-450 and cytochrome P-450-mediated peroxidases
Jing Zhang et al.
Journal of hazardous materials, 181(1-3), 1024-1030 (2010-06-18)
Methyl ethyl ketone peroxide (MEKPO) is widely used in polymer industry. It is highly sensitive to heat, friction, shock, flame or other sources of ignition, causing risks in production, storage and transportation. In this article, MEKPO is synthesized at a
M N Bozdemir et al.
Human & experimental toxicology, 30(12), 2002-2006 (2011-04-22)
Although ingestion of methyl ethyl ketone peroxide (MEKP) is rare, it carries a high risk of morbidity and mortality. This paper reports the first such case from Turkey in which a 70-year-old man unintentionally ingested MEKP in his kitchen. The
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