708682

RuCl[(R,R)-TsDPEN](mesitylene)

90%

• Sinônimo(s): [N-[(1R,2R)-2-(Amino-κN)-1,2- diphenylethyl]-4-methylbenzenesulfonamidato-κN]chloro [(1,2,3,4,5,6-η)-1,3,5-trimethylbenzene]-ruthenium
• Fórmula empírica (Notação de Hill): C₃₀H₃₃ClN₂O₂RuS
• Número CAS: 174813-82-2
• Peso molecular: 622.18
• Número MDL: MFCD12545951
• Código UNSPSC: 12352116
• ID de substância PubChem: 329762817
• NACRES: NA.22

Propriedades

• Nível de qualidade: 100
• Ensaio: 90%
• Formulário: solid
• pf: 241-249 °C
• grupo funcional: amine; phenyl
• temperatura de armazenamento: 2-8°C
• cadeia de caracteres SMILES: Cc1cc(C)cc(C)c1.Cc2ccc(cc2)S(=O)(=O)N([Ru]Cl)[C@@H]([C@H](N)c3ccccc3)c4ccccc4
• InChI: 1S/C21H21N2O2S.C9H12.ClH.Ru/c1-16-12-14-19(15-13-16)26(24,25)23-21(18-10-6-3-7-11-18)20(22)17-8-4-2-5-9-17;1-7-4-8(2)6-9(3)5-7;;/h2-15,20-21H,22H2,1H3;4-6H,1-3H3;1H;/q-1;;;+2/p-1/t20-,21-;;;/m1.../s1
• chave InChI: XBNBOGZUDCYNOJ-AGEKDOICSA-M

Descrição

Aplicação

Takasago Ligands and Complexes for Asymmetric Reactions

RuCl[(R,R)-TsDPEN](mesitylene) may be used as a catalyst to synthesize:

• (2R,3S)-4-Benzyl-2-(hydroxyphenylmethyl)morpholin-3-one from racemic N-benzyl-2-benzoyl-3-morpholinone via dynamic kinetic resolution-based asymmetric transfer hydrogenation (ATH).
• Chiral nonracemic δ-phenylseleno alcohols from δ-phenylseleno ketones via catalytic ATH reaction.

Informações legais

Sold in collaboration with Takasago for research purposes only. WO9720789

Informações de segurança

• Código de classe de armazenamento: 11 - Combustible Solids
• Classe de risco de água (WGK): WGK 3
• Ponto de fulgor (°F): Not applicable
• Ponto de fulgor (°C): Not applicable
• Equipamento de proteção individual: Eyeshields, Gloves, type N95 (US)