703915

RuCl(p-cymene)[(S,S)-Ts-DPEN]

• Sinônimo(s): [N-[(1S,2S)-2-(Amino-κN)-1,2-diphenylethyl]-4-methylbenzenesulfonamidato-κN]chloro[(1,2,3,4,5,6-η)-1-methyl-4-(1-methylethyl)benzene]-ruthenium
• Fórmula empírica (Notação de Hill): C₃₁H₃₅ClN₂O₂RuS
• Número CAS: 192139-90-5
• Peso molecular: 636.21
• Número MDL: MFCD14155881
• Código UNSPSC: 12352116
• ID de substância PubChem: 329762076
• NACRES: NA.22

Propriedades

• Formulário: solid
• Nível de qualidade: 100
• atividade óptica: [α]20/D +178°, c = 0.5 in chloroform
• pf: >175 °C
• grupo funcional: amine; phenyl
• temperatura de armazenamento: 2-8°C
• cadeia de caracteres SMILES: CC(C)c1ccc(C)cc1.Cc2ccc(cc2)S(=O)(=O)N([Ru]Cl)[C@H]([C@@H](N)c3ccccc3)c4ccccc4
• InChI: 1S/C21H21N2O2S.C10H14.ClH.Ru/c1-16-12-14-19(15-13-16)26(24,25)23-21(18-10-6-3-7-11-18)20(22)17-8-4-2-5-9-17;1-8(2)10-6-4-9(3)5-7-10;;/h2-15,20-21H,22H2,1H3;4-8H,1-3H3;1H;/q-1;;;+2/p-1/t20-,21-;;;/m0.../s1
• chave InChI: AZFNGPAYDKGCRB-XCPIVNJJSA-M

Descrição

Descrição geral

RuCl(p-cymene)[(S,S)-Ts-DPEN] is a chiral diamine ligand complexed with ruthenium, which can be used for the asymmetric transfer hydrogenation of a variety of imines.

Aplicação

Takasago Ligands and Complexes for Asymmetric Reactions

Catalyst involved in:

• Asymmetric transfer hydrogenation of imines and ketones
• Intramolecular asymmetric reductive amination
• Tandem hydroformylation / hydrogenation of terminal olefins

Reactant involved in studies of thermal decomposition of areneruthenium chiral amido-amine alkyl complexes

Informações legais

Sold in collaboration with Takasago for research purposes only. WO9720789

Informações de segurança

• Código de classe de armazenamento: 11 - Combustible Solids
• Classe de risco de água (WGK): WGK 3
• Ponto de fulgor (°F): Not applicable
• Ponto de fulgor (°C): Not applicable
• Equipamento de proteção individual: Eyeshields, Gloves, type N95 (US)