Pular para o conteúdo
Merck
Todas as fotos(4)

Key Documents

View All Documentation

703591

Sigma-Aldrich

Ethylmagnesium bromide solution

greener alternative

3.4 M in 2-methyltetrahydrofuran

Sinônimo(s):

Bromoethylmagnesium

Faça loginpara ver os preços organizacionais e de contrato
Todas as fotos(4)

About This Item

Fórmula linear:
CH3CH2MgBr
Número CAS:
925-90-6
Peso molecular:
133.27
Beilstein:
3587203
Número MDL:
MFCD00000043
Código UNSPSC:
12352103
ID de substância PubChem:
329762053
NACRES:
NA.22

forma

liquid

adequação da reação

reaction type: Grignard Reaction

características do produto alternativo mais ecológico

Safer Solvents and Auxiliaries
Use of Renewable Feedstocks
Inherently Safer Chemistry for Accident Prevention
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

concentração

3.4 M in 2-methyltetrahydrofuran
40 % (w/w)

densidade

1.142 g/mL at 25 °C

categoria alternativa mais ecológica

, Aligned

cadeia de caracteres SMILES

CC[Mg]Br

InChI

1S/C2H5.BrH.Mg/c1-2;;/h1H2,2H3;1H;/q;;+1/p-1

chave InChI

TWTWFMUQSOFTRN-UHFFFAOYSA-M

Procurando produtos similares? Visita Guia de comparação de produtos

Categorias relacionadas

Descrição geral

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product, 1.0 M in 2-methyltetrahydrofuran aligns with Safer Solvents and Auxiliaries, Use of Renewable Feedstocks and Inherently Safer Chemistry for Accident Prevention. Click here for more information.

Aplicação

Grignard reagent in greener solvent, 2-methyltetrahydrofuran (2-MeTHF)

2-Methyltetrahydrofuran (2-MeTHF): A Biomass-Derived Solvent with Broad Application in Organic Chemistry

Informações legais

Product of Albemarle US Inc

Palavra indicadora

Danger

Frases de perigo

H225,H260,H302,H314

Classificações de perigo

Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - Water-react 1

Perigos de suplementos

EUH014,EUH019

Código de classe de armazenamento

4.3 - Hazardous materials which set free flammable gases upon contact with water

Classe de risco de água (WGK)

WGK 2

Ponto de fulgor (°F)

24.8 °F - closed cup

Ponto de fulgor (°C)

-4 °C - closed cup

Equipamento de proteção individual

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

Escolha uma das versões mais recentes:

Certificados de análise (COA)

Lot/Batch Number
SHBN4706
SHBL2455
SHBL4748
SHBL5079
SHBK1769

Não está vendo a versão correta?

Se precisar de uma versão específica, você pode procurar um certificado específico pelo número do lote ou da remessa.

Pesquise por COA

Já possui este produto?

Encontre a documentação dos produtos que você adquiriu recentemente na biblioteca de documentos.

Visite a Biblioteca de Documentos

Os clientes também visualizaram

Slide 1 of 3

1 of 3

2-Methyltetrahydrofuran BioRenewable, anhydrous, ≥99.0%, contains 250 ppm BHT as stabilizer

Sigma-Aldrich

414247

2-Methyltetrahydrofuran

2-Methyltetrahydrofuran BioRenewable, anhydrous, ≥99%, Inhibitor-free

Sigma-Aldrich

673277

2-Methyltetrahydrofuran

Isopropóxido de titânio(IV) 97%

Sigma-Aldrich

205273

Isopropóxido de titânio(IV)

M Wältermann et al.
Microbiology (Reading, England), 146 ( Pt 5), 1143-1149 (2000-06-01)
The triacylglycerol (TAG)-accumulating, hydrocarbon-degrading bacterium Rhodococcus opacus strain PD630 and chemically induced storage-deficient mutants derived from this strain were investigated for their capability to accumulate storage lipids in the cytoplasm during cultivation under nitrogen-limiting conditions. Acylglycerols were analysed by matrix-associated
Janne E Tønder et al.
Organic & biomolecular chemistry, 2(10), 1447-1455 (2004-05-12)
Copper mediated allylic substitutions and conjugate additions to geranyl, cinnamyl and allylic indole compounds have been investigated with the aim of finding a method for the creation of the all-carbon quaternary centre present in the natural product lyngbyatoxin A. Reaction
R G Xie et al.
Steroids, 55(11), 488-490 (1990-11-01)
The reaction of ethyl magnesium bromide and 17 alpha-ethynylestradiol with formaldehyde in the presence of triethyl phosphate or hexamethylphosphoramide gave the 2- and 4-formyl-17 alpha-ethynylestradiol in high yield. Treatment of the formyl derivatives with an alkaline solution of hydrogen peroxide
T Nishiyama et al.
Chemical & pharmaceutical bulletin, 48(12), 1999-2002 (2001-01-06)
The direct alpha-bromination of various ketones using trifluoromethanesulfonic anhydride and Grignard reagent or magnesium bromide in ether gave the corresponding alpha-bromo ketones in moderate to good yields under mild reaction conditions.
F Turon et al.
Lipids, 37(8), 817-821 (2002-10-10)
An analytical procedure was developed for regiodistribution analysis of TAG using alpha-MAG prepared by an ethyl magnesium bromide deacylation. In the present communication, the deacylation procedure is shown to lead to representative alpha-MAG, allowing the composition of the native TAG
Exibir todos os documentos relacionados

Nossa equipe de cientistas tem experiência em todas as áreas de pesquisa, incluindo Life Sciences, ciência de materiais, síntese química, cromatografia, química analítica e muitas outras.

Entre em contato com a assistência técnica