564990

N,N-Diethyl-1,1,2,3,3,3-hexafluoropropylamine

• Sinônimo(s): Ishikawa’s Reagent
• Fórmula linear: CF₃CHFCF₂N(C₂H₅)₂
• Número CAS: 309-88-6
• Peso molecular: 223.16
• Número MDL: MFCD00054683
• Código UNSPSC: 12352101
• ID de substância PubChem: 24880211
• NACRES: NA.22

Propriedades

• índice de refração: n20/D 1.3460 (lit.)
• pb: 56-57 °C (lit.)
• densidade: 1.230 g/mL at 25 °C (lit.)
• cadeia de caracteres SMILES: CCN(CC)C(F)(F)C(F)C(F)(F)F
• InChI: 1S/C7H11F6N/c1-3-14(4-2)7(12,13)5(8)6(9,10)11/h5H,3-4H2,1-2H3
• chave InChI: BNTFCVMJHBNJAR-UHFFFAOYSA-N

Descrição

Descrição geral

GC analysis includes Et₂NCF=CFCF₃ (two isomers), both of which are active fluorinating agents.

Aplicação

Reactant for:

• Friedel-Crafts type arylation of hydrofluorocarbons
• Microbial hydroxylation of antibiotics
• Electrochemical fluorination of trialkylamines and tetraalkylammonium salts
• Fluorination of pyrethroides

Reactant for synthesis of:

• γ-Hydroxy-α-fluoro-α-trifluoromethylcarboxamide
• Florfenicol and thiamphenicol

Demonstrates utility in fluorination.

Displays the ability to insert a fluoro(trifluoromethyl) methylene moiety in unsaturated alcohols.

Informações de segurança

• Pictogramas: GHS02,GHS05
• Palavra indicadora: Danger
• Frases de perigo: H226,H314
• Declarações de precaução: P210 - P233 - P240 - P280 - P303 + P361 + P353 - P305 + P351 + P338
• Classificações de perigo: Flam. Liq. 3 - Skin Corr. 1B
• Código de classe de armazenamento: 3 - Flammable liquids
• Classe de risco de água (WGK): WGK 3
• Ponto de fulgor (°F): 104.0 °F - closed cup
• Ponto de fulgor (°C): 40 °C - closed cup
• Equipamento de proteção individual: Faceshields, Gloves, Goggles