420727
Chloro(dimethylsulfide)gold(I)
Sinônimo(s):
(Dimethylsulfide)gold(I) chloride
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About This Item
Fórmula linear:
(CH3)2SAuCl
Número CAS:
Peso molecular:
294.55
Número MDL:
Código UNSPSC:
12161600
ID de substância PubChem:
NACRES:
NA.22
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Formulário
powder
adequação da reação
core: gold
reagent type: catalyst
cadeia de caracteres SMILES
Cl[Au].CSC
InChI
1S/C2H6S.Au.ClH/c1-3-2;;/h1-2H3;;1H/q;+1;/p-1
chave InChI
YQALRAGCVWJXGB-UHFFFAOYSA-M
Aplicação
Chloro(dimethylsulfide)gold(I) can be used to synthesize a gold(I)-catalyst that can effectively catalyze intermolecular [2+2] cycloaddition of terminal alkynes with substituted alkenes to form substituted cyclobutenes under mild reaction conditions.
It can also be used to synthesize:
It can also be used to synthesize:
- chloro(trimesitylphosphine)gold(I)
- gold(I) N-heterocyclic carbene (NHC) complexes
- bis(carbene)gold(I) complex of ferrocenyl complexes
- gold(I) acetylide complexes
Palavra indicadora
Warning
Frases de perigo
Declarações de precaução
Classificações de perigo
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Órgãos-alvo
Respiratory system
Código de classe de armazenamento
11 - Combustible Solids
Classe de risco de água (WGK)
WGK 3
Ponto de fulgor (°F)
Not applicable
Ponto de fulgor (°C)
Not applicable
Equipamento de proteção individual
dust mask type N95 (US), Eyeshields, Gloves
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Chloro (dimethyl sulfide) gold (I)
Jones P G, et al.
Acta Crystallographica Section C, Crystal Structure Communications, 44(12), 2089-2091 (1988)
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