418099

Benzaldehyde

purified by redistillation, ≥99.5%

• Sinônimo(s): Bitter almond
• Fórmula linear: C₆H₅CHO
• Número CAS: 100-52-7
• Peso molecular: 106.12
• Beilstein: 471223
• Número CE: 202-860-4
• Número MDL: MFCD00003299
• Código UNSPSC: 12352100
• eCl@ss: 39023701
• ID de substância PubChem: 24866203
• NACRES: NA.22

Propriedades

• densidade de vapor: 3.7 (vs air)
• Nível de qualidade: 200
• pressão de vapor: 4 mmHg ( 45 °C)
• Ensaio: ≥99.5%
• Formulário: liquid
• temperatura de autoignição: 374 °F
• purificado por: redistillation
• Lim. expl.: 1.4 %, 20 °F
• índice de refração: n20/D 1.545 (lit.)
• pH: 5.9 (20 °C)
• p.e.: 178-179 °C (lit.)
• pf: −26 °C (lit.)
• densidade: 1.044 g/cm³ at 20 °C (lit.)
• grupo funcional: aldehyde; phenyl
• cadeia de caracteres SMILES: O=Cc1ccccc1
• InChI: 1S/C7H6O/c8-6-7-4-2-1-3-5-7/h1-6H
• chave InChI: HUMNYLRZRPPJDN-UHFFFAOYSA-N

Descrição

Descrição geral

Benzaldehyde (bitter-almond oil) is an aromatic compound commonly used in the cosmetics and flavor industries. The natural source of benzaldehyde is amygdalin, a glycoside found in apricots, bitter almonds, apples, cherries etc. Benzaldehyde is commercially produced by liquid phase chlorination and oxidation of toluene. Other methods reported to produce benzaldehyde include oxidation of benzyl alcohol, hydrolysis of benzal chloride and carbonylation of benzene.

Aplicação

Benzaldehyde can be used as a precursor to synthesize:

• Cinnamaldehyde, cinnamic acid, ethyl cinnamate, benzoic acid, benzyl alcohol, benzyl benzoate and hydrobenzamide etc.
• Triphenylmethane derivatives by condensation with phenols, aromatic amines, and benzene. This reaction is useful for the production of malachite green dyes.
• Benzoylborane by reacting with borylmagnesium bromides.
• Multi-benzaldehyde functionalized poly(ethylene glycol) analog which is used as a cross-linker to develop an injectable hydrogel system.

Informações de segurança

• Pictogramas: GHS08,GHS07,GHS09
• Palavra indicadora: Danger
• Frases de perigo: H302 + H332,H315,H319,H335,H360Df,H411
• Declarações de precaução: P273 - P301 + P312 - P302 + P352 - P304 + P340 + P312 - P305 + P351 + P338 - P308 + P313
• Classificações de perigo: Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Irrit. 2 - Repr. 1B - Skin Irrit. 2 - STOT SE 3
• Órgãos-alvo: Respiratory system
• Código de classe de armazenamento: 6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
• Classe de risco de água (WGK): WGK 1
• Ponto de fulgor (°F): 145.4 °F - closed cup
• Ponto de fulgor (°C): 63 °C - closed cup
• Equipamento de proteção individual: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter