393193

Hydrocinnamaldehyde

technical grade, 90%

• Sinônimo(s): 3-Phenylpropionaldehyde
• Fórmula linear: C₆H₅CH₂CH₂CHO
• Número CAS: 104-53-0
• Peso molecular: 134.18
• Beilstein: 1071910
• Número CE: 203-211-8
• Número MDL: MFCD00007021
• Código UNSPSC: 12352100
• ID de substância PubChem: 24864504
• NACRES: NA.22

Propriedades

• grau: technical grade
• Nível de qualidade: 100
• Ensaio: 90%
• Formulário: liquid
• Impurezas: <5% 3-phenyl-1-propanol
• índice de refração: n20/D 1.523 (lit.)
• p.e.: 97-98 °C/12 mmHg (lit.)
• densidade: 1.019 g/mL at 25 °C (lit.)
• grupo funcional: aldehyde; phenyl
• cadeia de caracteres SMILES: [H]C(=O)CCc1ccccc1
• InChI: 1S/C9H10O/c10-8-4-7-9-5-2-1-3-6-9/h1-3,5-6,8H,4,7H2
• chave InChI: YGCZTXZTJXYWCO-UHFFFAOYSA-N

Descrição

Descrição geral

Hydrocinnamaldehyde is C=C double bond hydrogenated cinnamaldehyde. It has been synthesized by the selective hydrogenation of C=C double bond of cinnamaldehyde by various methods. Hydrocinnamaldehyde and nitromethane undergoes Henry reaction to form nitroaldols. The C1 and C3 position labelled with ¹³C of hydrocinnamaldehyde was subjected to mass spectrometry and the fragmentation pattern was elucidated.

Aplicação

Hydrocinnamaldehyde may be used in the synthesis of the following:

• 2-Chloro hydrocinnamaldehyde by α-chlorination.
• Mixture of homopropargyl alcohols by kinetic resolution-allenylboration reactions.
• Mixture of syn- and anti-β-hydroxyallylsilanes by hydroboration of allenylsilane.
• (2S)-2-Hydroxy-4-phenylbutanenitrile by catalytic asymmetric cyanosilylation.
• Cinnamaldehyde by dehydrogenation reaction using Pd(TFA)₂/4,5-diazafluorenone catalyst.

Informações de segurança

• Código de classe de armazenamento: 10 - Combustible liquids
• Classe de risco de água (WGK): WGK 2
• Ponto de fulgor (°F): 203.0 °F - closed cup
• Ponto de fulgor (°C): 95 °C - closed cup
• Equipamento de proteção individual: Eyeshields, Gloves, type ABEK (EN14387) respirator filter