347116
Samarium(II) iodide solution
0.1 M in THF, contains samarium chips as stabilizer
Sinônimo(s):
Samarium diiodide
About This Item
Produtos recomendados
Formulário
liquid
Nível de qualidade
contém
samarium chips as stabilizer
adequação da reação
core: samarium
reagent type: catalyst
reaction type: Reductions
reagent type: reductant
concentração
0.1 M in THF
densidade
0.922 g/mL at 25 °C
temperatura de armazenamento
2-8°C
cadeia de caracteres SMILES
I[Sm]I
InChI
1S/2HI.Sm/h2*1H;/q;;+2/p-2
chave InChI
UAWABSHMGXMCRK-UHFFFAOYSA-L
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Categorias relacionadas
Aplicação
- Benzannulated pyrrolizidines and indolizidines by SmI2-induced cyclizations of indole derivatives.
- Chiral 4-substituted 2-oxazolidinones and 5,5-disubstituted oxazolidinones through asymmetric Reformatsky type reaction.
- γ-Aminoalkyl substituted γ-butyrolactones via ketyl-alkene coupling reaction.
It can also be used in:
- Reduction of conjugated double and triple bonds into alkenes using SmI2/H2O/amine mixtures.
- Conversion of β-hydroxyketones into 1,3-diols by SmI2/H2O/Et3N.
- Selective reduction of 6-membered lactones to the corresponding diols/triols using SmI2-H2O reagent system.
SmI2 is an effective single-electron reducing agent for the promotion of ketone-olefin, ketyl aryl cyclizations, and pinacol coupling reactions under mild conditions. Often both intramolecular and intermolecular couplings proceed in a highly stereoselective fashion. It is also used in the synthesis of new heteroleptic samarium aryloxide/cyclopentadienide complexes.
Embalagem
Informações legais
Palavra indicadora
Danger
Frases de perigo
Declarações de precaução
Classificações de perigo
Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3 - Water-react 3
Órgãos-alvo
Central nervous system, Respiratory system
Perigos de suplementos
Código de classe de armazenamento
4.3 - Hazardous materials which set free flammable gases upon contact with water
Classe de risco de água (WGK)
WGK 3
Ponto de fulgor (°F)
-2.2 °F - closed cup - Solvent
Ponto de fulgor (°C)
-19 °C - closed cup - Solvent
Equipamento de proteção individual
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
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Global Trade Item Number
| SKU | GTIN |
|---|---|
| 347116-1L | 4061826761533 |
| 347116-4X10ML | |
| 347116-4X25ML | 4061826761557 |
| 347116-PZ | 4061834279242 |
| 347116-100ML | 4061826761519 |
| 347116-25ML | 4061826761540 |
| 347116-5ML | |
| 347116-800ML |
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