345474
Lithium trimethylsilanolate
95%
Sinônimo(s):
Trimethylsilanol lithium salt
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About This Item
Fórmula linear:
(CH3)3SiOLi
Número CAS:
Peso molecular:
96.13
Beilstein:
3686900
Número MDL:
Código UNSPSC:
12352000
ID de substância PubChem:
NACRES:
NA.22
Produtos recomendados
Nível de qualidade
Ensaio
95%
Formulário
solid
cadeia de caracteres SMILES
[Li+].C[Si](C)(C)[O-]
InChI
1S/C3H9OSi.Li/c1-5(2,3)4;/h1-3H3;/q-1;+1
chave InChI
OXOZHAWWRPCVGL-UHFFFAOYSA-N
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Categorias relacionadas
Aplicação
- Enhanced process and composition control for atomic layer deposition with lithium trimethylsilanolate: This study reports on the novel lithium precursor, lithium trimethylsilanolate (LiTMSO), for atomic layer deposition, comparing it with other lithium precursors for improved process and composition control (Ruud et al., 2017).
- Trimethylsiloxy based metal complexes as electrolyte additives for high voltage application in lithium ion cells: The paper discusses the synthesis of lithium trimethylsilanolate and its use as an additive to enhance the performance of high voltage lithium ion cells (Imholt et al., 2017).
- Application of trimethylsilanolate alkali salts in organic synthesis: This review covers various applications of lithium trimethylsilanolate in organic synthesis, highlighting its role in different reactions (Bürglová and Hlaváč, 2018).
Palavra indicadora
Danger
Frases de perigo
Declarações de precaução
Classificações de perigo
Eye Dam. 1 - Skin Corr. 1B
Código de classe de armazenamento
8A - Combustible corrosive hazardous materials
Classe de risco de água (WGK)
WGK 3
Equipamento de proteção individual
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
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D M Hui et al.
Clinica chimica acta; international journal of clinical chemistry, 302(1-2), 171-188 (2000-11-14)
We developed a new assay method for fluoride anion (F(-)) a specific metabolite of sarin. Trimethyifluorosilane (TMFS) was derivatized from F(-) with trimethylsilanol, and TMFS was detected with a GC-flame ionization detector (FID) and capillary column system. The linear range
A Isquith et al.
Food and chemical toxicology : an international journal published for the British Industrial Biological Research Association, 26(3), 263-266 (1988-03-01)
Six organosilicon compounds which had been found to have clastogenic activity in an in vitro battery of genotoxicity assays were evaluated in rat bone marrow cytogenetic assays for assessing clastogenicity in an in vivo system. None of the six compounds
Igor S Ignatyev et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 60(5), 1169-1178 (2004-04-16)
The assignment of the SiOH group vibrations of trimethylsilanol, which is still controversial, is proposed. This assignment is based on theoretical B3LYP force field scaled using the constants of the (CH3)3Si group optimized to fit experimental vibrational frequencies of (CH3)3SiF
Fabricio A Hansel et al.
Rapid communications in mass spectrometry : RCM, 25(13), 1893-1898 (2011-06-04)
A methodology is presented for the determination of dihydroxy fatty acids preserved in the 'bound' phase of organic residues preserved in archaeological potsherds. The method comprises saponification, esterification, silica gel column chromatographic fractionation, and analysis by gas chromatography/mass spectrometry. The
Diane M Coe et al.
Organic & biomolecular chemistry, 1(7), 1106-1111 (2003-08-21)
A convenient and efficient method for the cleavage of 1,3-oxazolidin-5-ones and 1,3-oxazolidin-2-ones utilising potassium trimethylsilanolate in tetrahydrofuran is described. The benzyloxycarbonyl-protecting group is readily removed under the reaction conditions, whereas the N-benzoyl group is stable. A synthesis of (R)-salmeterol exploiting
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