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Sigma-Aldrich

Lithium trimethylsilanolate

95%

Sinônimo(s):

Trimethylsilanol lithium salt

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About This Item

Fórmula linear:
(CH3)3SiOLi
Número CAS:
2004-14-0
Peso molecular:
96.13
Beilstein:
3686900
Número MDL:
MFCD00075322
Código UNSPSC:
12352000
ID de substância PubChem:
24861324
NACRES:
NA.22

Ensaio

95%

forma

solid

cadeia de caracteres SMILES

[Li+].C[Si](C)(C)[O-]

InChI

1S/C3H9OSi.Li/c1-5(2,3)4;/h1-3H3;/q-1;+1

chave InChI

OXOZHAWWRPCVGL-UHFFFAOYSA-N

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Categorias relacionadas

Aplicação


  • Enhanced process and composition control for atomic layer deposition with lithium trimethylsilanolate: This study reports on the novel lithium precursor, lithium trimethylsilanolate (LiTMSO), for atomic layer deposition, comparing it with other lithium precursors for improved process and composition control (Ruud et al., 2017).

  • Trimethylsiloxy based metal complexes as electrolyte additives for high voltage application in lithium ion cells: The paper discusses the synthesis of lithium trimethylsilanolate and its use as an additive to enhance the performance of high voltage lithium ion cells (Imholt et al., 2017).

  • Application of trimethylsilanolate alkali salts in organic synthesis: This review covers various applications of lithium trimethylsilanolate in organic synthesis, highlighting its role in different reactions (Bürglová and Hlaváč, 2018).

Pictogramas

Corrosion
GHS05

Palavra indicadora

Danger

Frases de perigo

H314

Classificações de perigo

Eye Dam. 1 - Skin Corr. 1B

Código de classe de armazenamento

8A - Combustible corrosive hazardous materials

Classe de risco de água (WGK)

WGK 3

Equipamento de proteção individual

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

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D M Hui et al.
Clinica chimica acta; international journal of clinical chemistry, 302(1-2), 171-188 (2000-11-14)
We developed a new assay method for fluoride anion (F(-)) a specific metabolite of sarin. Trimethyifluorosilane (TMFS) was derivatized from F(-) with trimethylsilanol, and TMFS was detected with a GC-flame ionization detector (FID) and capillary column system. The linear range
A Isquith et al.
Food and chemical toxicology : an international journal published for the British Industrial Biological Research Association, 26(3), 263-266 (1988-03-01)
Six organosilicon compounds which had been found to have clastogenic activity in an in vitro battery of genotoxicity assays were evaluated in rat bone marrow cytogenetic assays for assessing clastogenicity in an in vivo system. None of the six compounds
Igor S Ignatyev et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 60(5), 1169-1178 (2004-04-16)
The assignment of the SiOH group vibrations of trimethylsilanol, which is still controversial, is proposed. This assignment is based on theoretical B3LYP force field scaled using the constants of the (CH3)3Si group optimized to fit experimental vibrational frequencies of (CH3)3SiF
Fabricio A Hansel et al.
Rapid communications in mass spectrometry : RCM, 25(13), 1893-1898 (2011-06-04)
A methodology is presented for the determination of dihydroxy fatty acids preserved in the 'bound' phase of organic residues preserved in archaeological potsherds. The method comprises saponification, esterification, silica gel column chromatographic fractionation, and analysis by gas chromatography/mass spectrometry. The
Diane M Coe et al.
Organic & biomolecular chemistry, 1(7), 1106-1111 (2003-08-21)
A convenient and efficient method for the cleavage of 1,3-oxazolidin-5-ones and 1,3-oxazolidin-2-ones utilising potassium trimethylsilanolate in tetrahydrofuran is described. The benzyloxycarbonyl-protecting group is readily removed under the reaction conditions, whereas the N-benzoyl group is stable. A synthesis of (R)-salmeterol exploiting
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